Cellulose acetate obtained from Schizolobium parahyba (vell.) blake wood

Authors

DOI:

https://doi.org/10.33448/rsd-v10i12.20761

Keywords:

Acetosolv pulping; acetosolv pulping; Cellulose acetate; cellulose acetate; DMA; membrane; Membrane; Schizolobium parahyba; Schizolobium parahyba.

Abstract

Currently, non-biodegradable polymers are produced on a large scale and cause several environmental problems, especially due to their low degradation. Cellulose acetate is a non-toxic, low-flammable and low-cost polymer, playing an important environmental role. The objective of this study was to synthesize cellulose acetate membranes from Schizolobium parahyba wood (“guapuruvu”) with particles sizes of 20 and 60 mesh. The materials were submitted to acetosolv pulping, bleaching and acetylation to produce the acetates. The yields and the degree of substitution were found. The fibers were chemically characterized and the samples obtained at each processing step were analyzed by FTIR. It was possible to prepare acetates from both granulometries wood. The FTIR analysis showed changes on the samples’ bands, indicating that the chemical processes were efficient. Cellulose acetate obtained from the 60 mesh material presented a higher degree of substitution (2.74 ± 0.12) when compared to the 20 mesh acetate (2.59 ± 0.13), showing that the particle size of the material influenced on the efficiency of the acetylation reaction. DMA tests have demonstrated that the 60 mesh membrane has higher flexibility and transparency when compared to the 20 mesh membrane.

Author Biographies

Leticia Sant'Anna Allesi, Foundation for Research Support of the State of São Paulo

Graduated in Forestry Engineering from the Federal University of São Carlos, Sorocaba campus (2016) with a sandwich period at the University of Montana. He has experience in the area of ​​Forest Resources and Forest Engineering. He holds a master's degree in Planning and Use of Renewable Resources from the Federal University of São Carlos, Sorocaba campus, where he developed research on cellulose acetate (2019). He currently works at the Foundation for Research Support of the State of São Paulo - FAPESP, in the Audit and Internal Inspection sector of the Comptroller General.

Graduated in Forestry Engineering from the Federal University of São Carlos, Sorocaba campus (2016) with a sandwich period at the University of Montana. He has experience in the area of ​​Forest Resources and Forest Engineering. He holds a master's degree in Planning and Use of Renewable Resources from the Federal University of São Carlos, Sorocaba campus, where he developed research on cellulose acetate (2019). He currently works at the Foundation for Research Support of the State of São Paulo- FAPESP, in the Audit and Internal Inspection sector of the Comptroller General.

Joelen Osmari da Silva, Universidade Federal de São Carlos

Graduated in Polymer Technology from the Faculty of Technology of Sorocaba (FATEC-SO), Master in Materials Science from the Federal University of São Carlos (UFSCar), where he worked with the synthesis of cellulose acetate from sugarcane bagasse for application as biomaterials. She is currently a PhD student in Materials Science at the Federal University of São Carlos (UFSCar), where she works in research related to the development of hydrogels for agricultural applications. Member of the Materials Research Group Lignocellulosics (GPML) from the Federal University of São Carlos (UFSCar) Campus Sorocaba. Operates in the areas of Polymers, including: lignocellulosic materials, polymers from renewable sources and biomaterials, in particular, cellulose and its derivatives and hydrogels.

Franciane Andrade de Pádua, Universidade Federal de São Carlos

Graduated in Forest Engineering from the Federal University of Lavras (2001), Master in Forest Engineering from the Federal University of Lavras (2004) and Ph.D. in Wood Science and Technology from the Federal University of Lavras (2009). She is currently a professor on the permanent staff of the Forest Engineering course at the Federal University of São Carlos - Sorocaba campus. He was President of the Brazilian Society of Science and Technology of Madeira (management 2017-2019). He has experience in the area of ​​Forest Resources and Forest Engineering, with an emphasis on Forest Biomass Quality, acting on the following topics: Waste, evaluation and destructive and non-destructive wood sampling.

Vagner Roberto Botaro, Universidade Federal de São Carlos

Graduated in Bachelor of Chemistry with technological attributions from the University of São Paulo (1987), Master in Physical Chemistry from the University of São Paulo (1992) and Ph.D. in Physical Chemistry from the University of São Paulo (1996). The postdoctoral research was carried out at the École Française de Paeterie et des Insdutries Graphiques ? Grenoble/Fr in the group of natural polymeric materials. He is currently an associate professor - Campus Sorocaba and Productivity Researcher at CNpq. He has experience in Chemistry, with an emphasis on Organic Physical Chemistry, working mainly on the following topics: Composite materials, cellulose, modification of polysaccharides, lignin, pulping processes, production of gels derived from polysaccharides, and use of vegetable fibers in composite materials.

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02/10/2021

How to Cite

ALLESI, L. S.; SILVA, J. O. da; PÁDUA, F. A. de; BOTARO, V. R. Cellulose acetate obtained from Schizolobium parahyba (vell.) blake wood. Research, Society and Development, [S. l.], v. 10, n. 12, p. e584101220761, 2021. DOI: 10.33448/rsd-v10i12.20761. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/20761. Acesso em: 26 dec. 2024.

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Vol. 10 No. 12

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Engineerings

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Copyright (c) 2021 Leticia Sant'Anna Allesi; Joelen Osmari da Silva; Franciane Andrade de Pádua; Vagner Roberto Botaro

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