Evaluation of polycyclic aromatic hydrocarbons (PAHs) in the corn drying process

Authors

DOI:

https://doi.org/10.33448/rsd-v10i16.22444

Keywords:

Biomass energy; Thermal energy; Column dryer; Carcinogenesis.

Abstract

The pre-processing of agricultural products has great importance in the quality of the product, the most critical process, is the drying of grains, in which thermal energy is demanded. Since biomass burning produces polycyclic aromatic hydrocarbons (PAHs), which can be associated with carcinogenesis The objective of this study was to perform an assessment of the presence of PAHs derived from the maize drying process using Cavaco burning as a fuel source.  The experiment was conducted in the municipality of Cascavel-Paraná, in a storage unit located in Colônia Melissa, using a Kepler Weber column dryer model ADS 150, with a capacity of 150 t/h, with an IMTAB chip burner, with capacity of 8,000,000 kcal/h. To assess the presence of PAHs, corn samples were collected at the entry of the product into the storage unit (control) and samples were collected after the drying process with two passes in the dryer, for five days, every hour during eight hours a day, in the period of harvest/2020. All results obtained were below the detectable limit of 0.6 µg/kg. It is concluded with this study that the drying process of corn using chips in burners does not significantly produce PAHs, thus not harming the quality of the grain.

References

Brasil. (2005). Ministério Da Saúde. Ministério Da Saúde Agência Nacional De Vigilância Sanitária. Brasilia.

Brooker, D. B., Bakker-Arkema, F. W., & Hall, C. W. (1992). Drying and storage of grains and oilseeds. Springer Science & Business Media.

Camargo, M. S. F. O., & Toledo, M. (2000). Hidrocarbonetos aromáticos policíclicos em margarina, creme vegetal e maionese. Food Science and Technology, 20, 51-55.

Camargo, M. C. R., & Toledo, M. C. F. (2003). Polycyclic aromatic hydrocarbons in Brazilian vegetables and fruits. Food control, 14(1), 49-53.

Cardoso, M. T., Carneiro, A. C. O., Damásio, R. A. P., Jacovine, L. A. G., Vital, B. R., Martins, M. C., & Santos, R. C. (2010). Effect of combustion carbonization gases on the gravimetric yield of Eucalyptus sp wood. Ciência da Madeira, 1(2), 20-31.

CEC – Commission Of The European Communities. Commission Regulation (EC) (2011) Setting of maximum levels for certain contaminants in foodstuffs. Regulation, (1881), 5-24.

Embrapa - Empresa Brasileira De Pesquisa Agropecuária. (2019). Jornal Eletrônico Da Embrapa Milho E Sorgo. 106. Http://Grao.Cnpms.Embrapa.Br/Noticia.Php?Ed=Nzg=&Id=Mza3.

Escarrone, A. L. V., Caldas, S. S., Furlong, E. B., Meneghetti, V. L., Fagundes, C. A. A., Arias, J. L. O., & Primel, E. G. (2014). Polycyclic aromatic hydrocarbons in rice grain dried by different processes: Evaluation of a quick, easy, cheap, effective, rugged and safe extraction method. Food chemistry, 146, 597-602.

Galinaro, C. A., & Franco, D. W. (2009). Polycyclic aromatic hydrocarbons (PAHS) in cachaça, rum, whiskey and alcohol fuel. Química nova, 32(6), 1447-1451.

Houessou, J. K., Maloug, S., Leveque, A. S., Delteil, C., Heyd, B., & Camel, V. (2007). Effect of roasting conditions on the polycyclic aromatic hydrocarbon content in ground Arabica coffee and coffee brew. Journal of agricultural and food chemistry, 55(23), 9719-9726.

Klautau, J. V. P. (2008). Análise experimental de uma fornalha a lenha de fluxo co-corrente para secagem de grăos. Curitiba.

Lee, K., & Shin, H. S. (2010). Determination of polycyclic aromatic hydrocarbons in commercial roasted coffee beans. Food Science and Biotechnology, 19(6), 1435-1440.

Lawrence, J. F., & Weber, D. F. (1984). Determination of polycyclic aromatic hydrocarbons in Canadian samples of processed vegetable and dairy products by liquid chromatography with fluorescence detection. Journal of Agricultural and Food Chemistry, 32(4), 794-797.

Lima, R. F., Dionello, R. G., Peralba, M. D. C. R., Barrionuevo, S., Radunz, L. L., & Júnior, F. W. R. (2017). PAHs in corn grains submitted to drying with firewood. Food chemistry, 215, 165-170.

McGrath, T. E., Chan, W. G., & Hajaligol, M. R. (2003). Low temperature mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose. Journal of Analytical and Applied Pyrolysis, 66(1-2), 51-70.

Menzie, C. A., Potocki, B. B., & Santodonato, J. (1992). Exposure to carcinogenic PAHs in the environment. Environmental science & technology, 26(7), 1278-1284.

Orecchio, S., Ciotti, V. P., & Culotta, L. (2009). Polycyclic aromatic hydrocarbons (PAHs) in coffee brew samples: analytical method by GC–MS, profile, levels and sources. Food and Chemical Toxicology, 47(4), 819-826.

Queiroz, D., Pereira, J., & Melo, E. Determinação de vazões mínimas de ar para secagem de milho em baixas temperaturas na região de Viçosa, Minas Gerais. Revista Brasileira de Armazenamento, 11, 1-12.

Souza, C. M. A. D., Queiroz, D. M. D., & Lacerda Filho, A. F. D. (2002). Simulação do processo de secagem de sementes de milho em camada fixa. Scientia Agricola, 59, 653-660.

Stanciu, G., Dobrinas, S., Birghila, S., & Popescu, M. (2008). Determination of organic compounds from different types of coffee by hplc and gc-ecd analysis. Environmental Engineering & Management Journal, 7(6).

Swallow, W. H., & WH, S. (1976). Survey of polycyclic aromatic hydrocarbons in selected foods and food additives available in New Zealand. New Zealand Journal of Science, 19, 407-412.

Tfouni, S. A. V., Vitorino, S. H. P., & Toledo, M. C. D. F. (2007). Efeito do processamento na contaminação de cana-de-açúcar e derivados por hidrocarbonetos policíclicos aromáticos. Food Science and Technology, 27, 76-82.

Tfouni, S. A., Serrate, C. S., Carreiro, L. B., Camargo, M. C., Teles, C. R., Cipolli, K. M., & Furlani, R. P. (2012). Effect of roasting on chlorogenic acids, caffeine and polycyclic aromatic hydrocarbons levels in two Coffea cultivars: Coffea arabica cv. Catuaí Amarelo IAC‐62 and Coffea canephora cv. Apoatã IAC‐2258. International Journal of Food Science & Technology, 47(2), 406-415.

Villela, F. A., & Peske, S. T. (1997). Tecnologia pós-colheita para arroz. Peske, ST; Nedel, JL; Barros, ACSA Produção de arroz irrigado. Pelotas: UFPel, 351-412.

Wandan, E. N., Elleingand, E. F., & Ndouba, A. M. (2011). A screening for benzo [a] pyrène in cocoa beans subjected to different drying methods during on farm processing. International Journal of Engineering, Science and Technology, 3, 3621-3630.

Williams, P. T., & Horne, P. A. (1995). Analysis of aromatic hydrocarbons in pyrolytic oil derived from biomass. Journal of Analytical and Applied pyrolysis, 31, 15-37.

Wretling, 1. S., Eriksson, A., Eskhult, G. A., & Larsson, B. (2010). Polycyclic aromatic hydrocarbons (PAHs) in Swedish smoked meat and fish. Journal of food composition and analysis, 23(3), 264-272.

Yang, H. H., Lee, W. J., Chen, S. J., & Lai, S. O. (1998). PAH emission from various industrial stacks. Journal of Hazardous materials, 60(2), 159-174.

Zebek, M. S. (1980). Polycyclic aromatic hydrocarbon’: A review. Journal of Environmental Pathology, Toxicology and Oncology, 3, 537-567.

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Published

15/12/2021

How to Cite

MAFRA, J. B.; SANTOS , R. F. .; VENTURELLI , G. M.; BASSEGIO, D.; COELHO , S. R. M. .; SIMONETTI , A. P. M. M. .; BRANCO , T. M. .; BRANCO, K. C. . Evaluation of polycyclic aromatic hydrocarbons (PAHs) in the corn drying process. Research, Society and Development, [S. l.], v. 10, n. 16, p. e403101622444, 2021. DOI: 10.33448/rsd-v10i16.22444. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/22444. Acesso em: 26 dec. 2024.

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Section

Agrarian and Biological Sciences