Influence of crosslinking agent and EVA residues on the properties of EVA boards used in the footwear industry
DOI:
https://doi.org/10.33448/rsd-v11i8.31488Keywords:
EVA; Polymeric Foam; Crosslinking Agent; Blowing Agent; EVA Residue.Abstract
The ethylene-vinyl acetate (EVA) copolymer is a thermoplastic copolymer, with an elastomeric character, consisting of ethylene and vinyl acetate monomers. In the form of foams, it has been widely used in the footwear industry, especially in insoles. For the manufacture of an EVA foam, the main additives used are a crosslinking and expanding agent. The generation of waste from the footwear industry, specifically, the copolymer of ethylene and vinyl acetate (EVA), is related to the production process of shoe soles, insoles and insoles. Thus, the objective of this work is to study the concentration of crosslinking agent and EVA residue concentration in the properties of expanded EVA boards, seeking to understand how each one of them changes the final properties of the material. The friends were prepared in a bunbury mixer at 120ºC for 4 minutes and then homogenized in an open mixing cylinder for 2 minutes and molding of EVA plates was performed by thermal pressing at 165ºC. Expanded and were characterized by physical (density) and mechanical (permanent deformation by compression and hardness) tests, in addition to rheological tests. Rheometry results showing the addition of EVA residue and the increased concentration of crosslinking agent in them caused an increase in material viscosity during processing. The addition of residue and increase in the concentration of peroxide caused an increase in hardness and density density, the increase in density influenced lower values of DPC.
References
ASTM D395-18. (2018); Standard Test Methods for Rubber Property - Compression Set. ASTM International, West Conshohocken, PA, United States.
Durmus, A., Alanalp, M. B., & Aydin, I. (2018). Investigation of morphological, rheological, and mechanical properties of cyclic olefin copolymer/poly (ethylene-co-vinyl acetate) blend films. Journal of Plastic Film & Sheeting, 34(2), 140-159.
Estrela, C. (2018). Metodologia Científica: Ciência, Ensino, Pesquisa. Editora Artes Médicas.
Hobeika, S., Men, Y., & Strobl, G. (2000). Temperature and strain rate independence of critical strains in polyethylene and poly (ethylene-co-vinyl acetate). Macromolecules, 33(5), 1827-1833.
Hui, J., Xia, H., Chen, H., Qiu, Y., Fu, Y., & Ni, Q. Q. (2020). Two-way reversible shape memory polymer: Synthesis and characterization of benzoyl peroxide-crosslinked poly (ethylene-co-vinyl acetate). Materials Letters, 258, 126762.
Lu, H., Li, Z., Qi, X., Xu, L., Chi, Z., Duan, D., ... & Dong, Y. (2021). Flexible, electrothermal-driven controllable carbon fiber/poly (ethylene-co-vinyl acetate) shape memory composites for electromagnetic shielding. Composites Science and Technology, 207, 108697.
Machado, A. L., Lucas, E. F., & González, G. (2001). Poly (ethylene-co-vinyl acetate) (EVA) as wax inhibitor of a Brazilian crude oil: oil viscosity, pour point and phase behavior of organic solutions. Journal of Petroleum Science and Engineering, 32(2-4), 159-165.
Nofar, M., Sacligil, D., Carreau, P. J., Kamal, M. R., & Heuzey, M. C. (2019). Poly (lactic acid) blends: Processing, properties and applications. International journal of biological macromolecules, 125, 307-360.
Osman, A. F., Hamid, A. R. A., Fitri, T. F. M., Fauzi, A. A. A., & Halim, K. A. A. (2020, May). Poly (ethylene-co-vinylacetate) copolymer-based nanocomposites: a review. In IOP Conference Series: Materials Science and Engineering (Vol. 864, No. 1, p. 012121). IOP Publishing.
Rimez, B., Rahier, H., Van Assche, G., Artoos, T., Biesemans, M., & Van Mele, B. (2008). The thermal degradation of poly (vinyl acetate) and poly (ethylene-co-vinyl acetate), Part I: Experimental study of the degradation mechanism. Polymer Degradation and Stability, 93(4), 800-810.
Sessini, V., Raquez, J. M., Kenny, J. M., Dubois, P., & Peponi, L. (2019). Melt-processing of bionanocomposites based on ethylene-co-vinyl acetate and starch nanocrystals. Carbohydrate polymers, 208, 382-390.
Zhang, N., & Lu, X. (2016). Morphology and properties of super-toughened bio-based poly (lactic acid)/poly (ethylene-co-vinyl acetate) blends by peroxide-induced dynamic vulcanization and interfacial compatibilization. Polymer Testing, 56, 354-363.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2022 Rafael Braga da Cunha; Ytalo Ouriques Rodrigues; Tomas Jeferson Alves de Melo
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3) Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.