Discrete pore and particle size distributions during pore blocking and cake filtration

Authors

DOI:

https://doi.org/10.33448/rsd-v13i1.44702

Keywords:

Microfiltration; Straining; Pore blocking; Cake build-up; Pore and particle size distributions.

Abstract

Modeling membrane filtration is important for plenty industrial applications. The understanding of the phenomena and related mechanisms aims at the improvement of techniques in different areas. Therefore, different authors have proposed models to describe the mechanisms related to the filtration process involving either cake build-up or blocking processes, a few of them however have proposed both concepts simultaneously, although none considered pore and particle size distribution during the process, which is the proposal brought up in this paper. Transient solutions for filtrate volume and filter cake thickness as a function of initial pore and particle size distributions are obtained. Good matching between the studied experimental data and the proposed model was observed. In general, the results showed that permeability reduction and filtrate volume are strongly influenced by the initial pore and particle size distributions. In addition, the cake build-up rate depends on both the particle size distribution and the residual flow through blocked pores. It was observed that, after all the largest particles have blocked the smaller pores, effective permeability and flow rate vary only due to cake build-up. Finally, because the proposed empirical parameters do not depend on the pore size distribution, this model can be applied for predicting permeability decline for any feed concentration.

References

Bolton, G., LaCasse, D., & Kuriyel, R. (2006). Combined models of membrane fouling: Development and application to microfiltration and ultrafiltration of biological fluids, Journal of Membrane Science. 277, 75–84.

Bowen W. R., Calvo J. I., & Hernandez A. (1995). Steps of membrane blocking in flux decline during protein microfiltration, Journal of Membrane Science, 101, 153.

Filippov A., Starov V. M., Lloyd D. R., Chakravarti S., & Glaser S. (1994). Sieve mechanism of microfiltration, Journal of Membrane Science. 89, 199–213.

Gonsalves V. E. (1950). A critical investigation on the viscose filtration. Rec. Trav. Chim. Des Pays-Bas, 69, 873.

Goodwin J. W., Hearn J., Ho C. C., & Ottewill R. H. (1974). Studies on the preparation and characterisation of monodisperse polystyrene laticee, Colloid and Polymer Science, 252: 464–471.

Grace H. P. (1956). Structure and performance of filter media. AIChE Journal, 2.

Herzig J. P., Leclerc D. M., & Le Goff P. (1970). Flow of suspensions through porous media application to deep filtration, Ind. Eng. Chem. 62:8–35.

Hermans P. H., & Bredée H. L. (1935). Zur Kenntnis der Filtrationsgesetze, Recl. Trav. Chim. Pays-Bas, 54:680–700.

Hlavacek M., & Bouchet F. (1993). Constant flowrate blocking laws and an example of their application to dead-end microfiltration of protein solutions, Journal of Membrane Science, 82, 285.

Ho C. C., & Zydney A. L. (2000). A Combined Pore Blockage and Cake Filtration Model for Protein Fouling during Microfiltration, Journal of Colloid and Interface Science, 232:389–399.

Kosvintsev S., Cumming I., Holdich R., Lloyd D., & Starov V. (2004). Sieve mechanism of microfiltration separation, Colloids and Surfaces A: Physicochemical and Engineering, 230:167–182.

Kosvintsev S., Holdich R., Cumming I., Lloyd D., & Starov V. (2002). Modelling of dead-end microfiltration with pore blocking and cake formation, Journal of Membrane Science, 208:181–192.

Polyakov Y. S., & Zydney A. L. (2013). Ultrafiltration membrane performance: Effects of pore blockage/constriction. Journal of Membrane Science. 434, 106-120.

Ruth B. F., Montillon G. H., & Montonna R. E. (1933). Studies in Filtration-I. Critical Analysis of Filtration Theory, Industrial and Engineering Chemistry, 25(1), 76-82.

Ruth B. F. (1935). Studies in Filtration-III. Derivation of General Filtration Equation, Industrial and Engineering Chemistry, 27(6), 708-723.

Santos A., & Bedrikovetsky P. (2006). A stochastic model for particulate suspension flow in porous media, Transport in Porous Media, 62:23–53.

Santos A., Bedrikovetsky P., & Fontoura S. (2008). Analytical micro model for size exclusion: Pore blocking and permeability reduction, Journal of Membrane Science, 308: 115–127.

Santos A., & Bedrikovetsky P. (2004). Size exclusion during particle suspension transport in porous media: stochastic and averaged equations, Computational and Applied Mathematics, 23: 259–284.

Shapiro A. A., Bedrikovetsky P. G., Santos A., & Medvedev O. O. (2007). A stochastic model for filtration of particulate suspensions with incomplete pore plugging, Transport in Porous Media, 67:135.

Sharma M. M., & Yortsos Y. C. (1987). Transport of particulate suspensions in porous media: model formulation, AICHE Journal, 33:1636-1643.

Tracey E. M., & Davis R. H. (1994). Protein fouling of track-etched polycarbonate microfiltration membranes, Journal of Colloid and Interface Science, 1676, 104.

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Published

06/01/2024

How to Cite

TARIFA, J. M.; SANTOS, A. dos . Discrete pore and particle size distributions during pore blocking and cake filtration. Research, Society and Development, [S. l.], v. 13, n. 1, p. e3213144702, 2024. DOI: 10.33448/rsd-v13i1.44702. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/44702. Acesso em: 21 nov. 2024.

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Section

Engineerings