Adsorção do corante amarelo ácido 17 em carvão ativado preparado do cacho do açaí Euterpe oleracea: estudos cinéticos e termodinâmico
DOI:
https://doi.org/10.33448/rsd-v11i2.25556Palavras-chave:
Adsorção; Carvão ativado; Amarelo ácido 17.Resumo
A poluição do meio ambiente tem sido ponto de discussão na comunidade internacional e objeto de investigação por grupos de pesquisa, que têm buscado o desenvolvimento de métodos de remediação. No presente estudo, o cacho de açaí (Euterpe oleracea) foi utilizado como precursor de carvão ativado de baixo custo para a remoção do corante amarelo ácido 17 (AY 17) em solução aquosa. A síntese foi realizada nas temperaturas de 500, 600 e 700 ° C, por 2,0 h em forno mufla. O mecanismo cinético e termodinâmico do processo de adsorção do corante AY 17, e os efeitos do pH, tempo de contato e concentração inicial foram investigados para o carvão ativado com maior capacidade adsortiva. O carvão ativado carbonizado a 700 °C teve a maior capacidade adsortiva, cerca de 99,9% de remoção do AY. A capacidade de adsorção de AY 17 é ligeiramente dependente do pH, com um valor máximo em pH 2,0. Os dados cinéticos mostram que o tempo de equilíbrio é de 200 min, e a capacidade de adsorção do carvão ativado foi de 99,9% a 50 mg L‒ 1 e 67,0% a 150 mg L‒1 de adsorbato, sugerindo alta capacidade de adsorção do material, mesmo na presença de alta concentração de corante. O processo de adsorção de AY 17 é descrito pelo modelo cinético de pseudo-segunda ordem, e as isotermas experimentais de adsorção são ajustadas ao modelo de Freundlich, indicando que a adsorção de AY 17 no carvão ativado ocorre com a formação de multicamadas. O presente estudo mostra que esse material de baixo custo possui grande potencial para remediação de efluentes têxteis.
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