Utilização do resíduo da hidrodestilação do óleo essencial de pimenta rosa (Schinus terebinthifolius Raddi) na proteção contra corrosão de aço carbono em meio HCl

Autores

DOI:

https://doi.org/10.33448/rsd-v11i13.35797

Palavras-chave:

Corrosão; Inibidor natural; Pimenta rosa; SVET; Isotérmicas de adsorção.

Resumo

In this research, different concentrations of the powder of the solid residue from the hydrodistillation of the pink pepper leaf (PRHPPL), generated in the production of its essential oil, were evaluated as an inhibitor for carbon steel in HCl 0.5 mol L-1. This evaluation was performed using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, scanning vibrating electrode technique (SVET), and mass loss tests. All tests showed that the highest concentration of the inhibitor (1.77 g L-1) presented better efficiency; from icorr, this efficiency was 98 %, from the equivalent circuit model Rct value it was 98 % and by the gravimetric test it was 86 %. Different isotherms were tested in order to better understand the adsorption process of the inhibitor molecules on the metal surface and the best fit was found for the Langmuir isotherm. The morphology of the steel surface was also analyzed by scanning electron microscopy (SEM).  This study reveals that this residue obtained from the production of essential oils can be used as corrosion inhibitor in the replacement to synthetic inhibitors.

Biografia do Autor

Nayara Maria Santos de Almeida, State University of Santa Cruz

Science and Technology Department Science, Innovation and Modeling Post-Graduate Program (PROCIMM)

Iago Magella Fernandes Costa Rossi e Silva, State University of Santa Cruz

Science and Technology Department Science, Innovation and Modeling Post-Graduate Program (PROCIMM)

Brunela Pereira da Silva, University of São Paulo

Polytechnic School
Department of Chemical Engineering  

Fernando Cotting, Federal University of Minas Gerais

Department of Chemical Engineering

Idalina Vieira Aoki, University of São Paulo

Polytechnic School
Department of Chemical Engineering

Vera Rosa Capelossi, State University of Santa Cruz

Science and Technology Department Science, Innovation and Modeling Post-Graduate Program (PROCIMM)

Referências

Anupama, K. K., Ramya, K., & Joseph, A. (2017). Electrochemical measurements and theoretical calculations on the inhibitive interaction of Plectranthus amboinicus leaf extract with mild steel in hydrochloric acid. Measurement, 95, 297-305.

Al Hasan, N. H. J., Alaradi, H. J., Al Mansor, Z. A. K., & Al Shadood, A. H. J. (2019). The dual effect of stem extract of Brahmi (Bacopamonnieri) and Henna as a green corrosion inhibitor for low carbon steel in 0.5 M NaOH solution. Case Studies in Construction Materials, 11, e00300.

Baranauskienė, R., Bendžiuvienė, V., Ragažinskienė, O., & Venskutonis, P. R. (2019). Essential oil composition of five Nepeta species cultivated in Lithuania and evaluation of their bioactivities, toxicity and antioxidant potential of hydrodistillation residues. Food and Chemical Toxicology, 129, 269-280.

Barreto, L. S., Tokumoto, M. S., Guedes, I. C., Melo, H. G. D., Amado, F. D. R., & Capelossi, V. R. (2017). Evaluation of the anticorrosion performance of peel garlic extract as corrosion inhibitor for ASTM 1020 carbon steel in acidic solution. Matéria (Rio de Janeiro), 22.

Barreto, L. S., Tokumoto, M. S., Guedes, I. C., Melo, H. G. D., Amado, F., & Capelossi, V. R. (2018). Study and Assessment of the Efficiency of the Cocoa Bark Extracted from the Theobroma Cacao as an Inhibitor of the Corrosion of Carbon Steel in Substitution of Benzotriazole. Materials Research, 21.

Carvalho, M. C. F. D., Almeida, N. M. S. D., Silva, I. M. F. C. R., Cotting, F., Aoki, I. V., & Capelossi, V. R. (2022). Electrochemical and Economic Evaluation of the Cocoa Bean Shell as a Corrosion Inhibitor in Acidic Medium. Materials Research, 25.

Divya, P., Subhashini, S., Prithiba, A., & Rajalakshmi, R. (2019). Tithonia diversifolia flower extract as green corrosion inhibitor for mild steel in acid medium. Materials Today: Proceedings, 18, 1581-1591.

Elyemni, M., Louaste, B., Nechad, I., Elkamli, T., Bouia, A., Taleb, M., & Eloutassi, N. (2019). Extraction of essential oils of Rosmarinus officinalis L. by two different methods: Hydrodistillation and microwave assisted hydrodistillation. The Scientific World Journal, 2019.

Fateh, A., Aliofkhazraei, M., & Rezvanian, A. R. (2020). Review of corrosive environments for copper and its corrosion inhibitors. Arabian journal of Chemistry, 13(1), 481-544.

Hussin, M. H., Rahim, A. A., Ibrahim, M. N. M., & Brosse, N. (2016). The capability of ultrafiltrated alkaline and organosolv oil palm (Elaeis guineensis) fronds lignin as green corrosion inhibitor for mild steel in 0.5 M HCl solution. Measurement, 78, 90-103.

Ituen, E., Akaranta, O., James, A., & Sun, S. (2017). Green and sustainable local biomaterials for oilfield chemicals: Griffonia simplicifolia extract as steel corrosion inhibitor in hydrochloric acid. Sustainable materials and technologies, 11, 12-18.

Loto, R. T., Leramo, R., & Oyebade, B. (2018). Synergistic Combination Effect of Salvia officinalis and Lavandula officinalis on the Corrosion Inhibition of Low-Carbon Steel in the Presence of SO42−-and Cl−-Containing Aqueous Environment. Journal of Failure Analysis and Prevention, 18(6), 1429-1438.

Mahomoodally, F., Aumeeruddy-Elalfi, Z., Venugopala, K. N., & Hosenally, M. (2019). Antiglycation, comparative antioxidant potential, phenolic content and yield variation of essential oils from 19 exotic and endemic medicinal plants. Saudi journal of biological sciences, 26(7), 1779-1788.

Ogunleye, O. O., Arinkoola, A. O., Eletta, O. A., Agbede, O. O., Osho, Y. A., Morakinyo, A. F., & Hamed, J. O. (2020). Green corrosion inhibition and adsorption characteristics of Luffa cylindrica leaf extract on mild steel in hydrochloric acid environment. Heliyon, 6(1), e03205.

Palanisamy, S. P., Maheswaran, G., Kamal, C., & Venkatesh, G. (2016). Prosopis juliflora—A green corrosion inhibitor for reinforced steel in concrete. Research on Chemical Intermediates, 42(12), 7823-7840.

Saeed, M. T., Saleem, M., Niyazi, A. H., Al-Shamrani, F. A., Jazzar, N. A., & Ali, M. (2020). Carrot (Daucus carota L.) peels extract as an herbal corrosion inhibitor for mild steel in 1M HCl solution. Modern Applied Science, 14(2), 97-112.

Shalabi, K., & Nazeer, A. A. (2015). Adsorption and inhibitive effect of Schinus terebinthifolius extract as a green corrosion inhibitor for carbon steel in acidic solution. Protection of Metals and Physical Chemistry of Surfaces, 51(5), 908-917.

Sanaei, Z., Ramezanzadeh, M., Bahlakeh, G., & Ramezanzadeh, B. (2019). Use of Rosa canina fruit extract as a green corrosion inhibitor for mild steel in 1 M HCl solution: A complementary experimental, molecular dynamics and quantum mechanics investigation. Journal of industrial and engineering chemistry, 69, 18-31.

Santana, J. S., Sartorelli, P., Guadagnin, R. C., Matsuo, A. L., Figueiredo, C. R., Soares, M. G., & Lago, J. H. G. (2012). Essential oils from Schinus terebinthifolius leaves–chemical composition and in vitro cytotoxicity evaluation. Pharmaceutical Biology, 50(10), 1248-1253.

Santos, A. D. M., Almeida, T. F. D., Cotting, F., Aoki, I. V., Melo, H. G. D., & Capelossi, V. R. (2017). Evaluation of castor bark powder as a corrosion inhibitor for carbon steel in acidic media. Materials Research, 20, 492-505.

Santos, A. M., Aquino, I. P., Cotting, F., Aoki, I. V., De Melo, H. G., & Capelossi, V. R. (2021). Evaluation of palm kernel cake powder (Elaeis guineensis Jacq.) as corrosion inhibitor for carbon steel in acidic media. Metals and Materials International, 27(6), 1519-1530.

Speight, J. G. (2014). Oil and gas corrosion prevention: From surface facilities to refineries. Gulf Professional Publishing.

Tolulope Loto, R., & Olowoyo, O. (2018). Corrosion inhibition properties of the combined admixture of essential oil extracts on mild steel in the presence of SO42− anions. South African Journal of Chemical Engineering, 26(1), 35-41.

Uhlig, H. H. (1971) Corrosion and corrosion control: An introduction to corrosion science and engineering. (2a. ed.) John Wiley: New York.

Uliana, M. P., Fronza, M., da Silva, A. G., Vargas, T. S., de Andrade, T. U., & Scherer, R. (2016). Composition and biological activity of Brazilian rose pepper (Schinus terebinthifolius Raddi) leaves. Industrial Crops and Products, 83, 235-240.

Umoren, S. A., Solomon, M. M., Obot, I. B., & Suleiman, R. K. (2019). A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals. Journal of Industrial and Engineering Chemistry, 76, 91-115.

Veličković, D. T., Milenović, D. M., Ristić, M. S., & Veljković, V. B. (2008). Ultrasonic extraction of waste solid residues from the Salvia sp. essential oil hydrodistillation. Biochemical Engineering Journal, 42(1), 97-104.

Zaher, A., Chaouiki, A., Salghi, R., Boukhraz, A., Bourkhiss, B., & Ouhssine, M. (2020). Inhibition of mild steel corrosion in 1M hydrochloric medium by the methanolic extract of Ammi visnaga L. Lam seeds. International Journal of Corrosion, 2020.

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Publicado

11/10/2022

Como Citar

ALMEIDA, N. M. S. de; SILVA, I. M. F. C. R. e .; SILVA, B. P. da .; COTTING, F. .; AOKI, I. V.; VELOSO, T. C. .; CAPELOSSI, V. R. Utilização do resíduo da hidrodestilação do óleo essencial de pimenta rosa (Schinus terebinthifolius Raddi) na proteção contra corrosão de aço carbono em meio HCl. Research, Society and Development, [S. l.], v. 11, n. 13, p. e433111335797, 2022. DOI: 10.33448/rsd-v11i13.35797. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/35797. Acesso em: 30 jun. 2024.

Edição

Seção

Engenharias