The chemistry and technology of dulce de leche: a review

Authors

DOI:

https://doi.org/10.33448/rsd-v10i11.19408

Keywords:

Dulce de Leche; Buffering Capacity; Maillard Reaction ; Rheology; Texture.

Abstract

Dulce de leche, a dairy dessert highly consumed in Latin American countries, is obtained from the evaporation of water from milk added with sugar. The heat treatment associated with evaporation triggers several chemical changes that directly influence the characteristics of the final product. Despite having few ingredients in its formulation, the final product can present very different characteristics depending on the processing conditions and of the controlled parameters. Therefore, it is evident that knowledge of topics such as the buffering capacity of milk, the use of acidity regulators, Maillard reaction and the main factors that affect its occurrence, rheology and texture, are extremely important in the manufacture of dulce de leche. The purpose of article is to review the main chemical reactions involved in the processing of dulce de leche and relate them to the characteristics obtained in the product.

References

Ahmed, J.; Ptaszek, P. & Basu, S. (2017). Food Rheology: Scientific Development and Importance to Food Industry. Food Science, Technology and Nutrition, 1- 4.

ABNT NBR ISO 11036, de 28 de agosto de 2017. Análise sensorial - Metodologia - Perfil de textura. Associação Brasileira De Normas Técnicas.

Bertrand, E., Boustany, E. P., Faulds, C. & Berdagué, J. (2018). The maillard reaction in food: an introduction. Reference Module in Food Science, 1–10.

Blanco, A. R., Piagentini, A., Rozycki, S., Lema, A., Pauletti, M. S. & Panizzolo, L. A. (2012). Evolución del desarrollo del color en sistema modelo de composición similar al dulce de leche. Influencia del tiempo de calentamiento y del pH. Revista Del Laboratorio Tecnológico Del Uruguay. 7 .

BRASIL. (1997a). Portaria nº 354, de 4 de setembro de 1997, do Ministério da Agricultura, Pecuária e Abastecimento. Aprova o Regulamento Técnico de Identidade e Qualidade de Doce de Leite. Diário Oficial da República Federativa do Brasil.

BRASIL. (1997b). Portaria SVS/MS nº 540, de 27 de outubro de 1997, do Ministério da Saúde. Secretaria de Vigilância Sanitária. Aprova o Regulamento Técnico: Aditivos Alimentares - definições, classificação e emprego. Diário Oficial da República Federativa do Brasil.

Brown, T. L., Lemay, H. E., Bursten, B. E., Murphy, C., Woodward, P. & Stoltzfus, M. E. (2017). Chemistry: The central science. (14a ed.), Pearson.

Carneiro, L. C. M., Perrone, I. T., Pinto, C. B. A., Oliveira, L. F. C., Wolfschoon-Pombo, A. F., Carvalho, A. F. & Stephani, R. (2020). Influência de diferentes reguladores de acidez na estabilização coloidal do leite e nas características físico-químicas de doce de leite. Indústria de Laticínios, 142, 68-74.

Damodaran, S., Parkin, K. L., Fennema, O. R. (2008). Fennema's Food Chemistry. (4a ed.), CRC Press/Taylor & Francis.

Francisquini, J. D., Rocha, J., Martins, E., Stephani, R., Silva, P. H. F., Renhe, I. R. T., Perrone, I. T. & Carvalho, A. (2019). 5-Hydroxymethylfurfural formation and color change in lactose-hydrolyzed Dulce de leche. Journal of Dairy Research, 86, 477-482.

Francisquini, J. D., Martins, E., Silva, P. H. F., Shuck, P., Perrone, I. T. & Carvalho, A. F. (2017). Reação de maillard: uma revisão. Revista do Instituto de Laticínios Cândido Tostes 72 (1), 48-57.

Fox, P. F. (1998). Developments in Dairy Chemistry - 3: Lactose and Minor Constituents. (2a ed.), Elsevier Applied Science Publishers.

Gavahian, M., Tiwari, B. K., Chu, Y., Ting, Y. & Farahnaky, A. (2019). Food texture as affected by ohmic heating: Mechanisms involved, recent findings, benefits, and limitations. Trends in Food Science and Technology, 86, 328–339.

Gaze, L. V., Costa, M. P., Monteiro, M. L. G., Lavorato, J. A. A., Junior, C. A. C., Raices, R. S. L., Cruz, A. G. & Freitas, M. Q. (2015). Dulce de Leche, a typical product of Latin America: characterisation by physicochemical, optical and instrumental methods. Food Chemistry, 169, 471– 477.

Giménez, A., Ares, G. & Gámbaro, A. (2008). Consumer perception of sandiness in dulce de leche. Journal of Sensory Studies, 23, 171-185.

Guimarães, J. T., Balthazar, C. F., Silva, R., Rocha, R. S., Graça, J. S., Esmerino, E. A., Silva, M. C., Sant'Ana, A. S., Duarte, M. C. K. H., Freitas, M. Q. & Cruz, A. G. (2020). Impact of probiotics and prebiotics on food texture. Current Opinion in Food Science, 33, 38–44.

Hough, G., Moro, O., Segura, J. & Calvo, N. (1988). Flow properties of dulce de leche, a typical argentine dairy product. Journal of Dairy Science, 71 (7), 1783-1788.

Hough, G., Martinez, E. & Contarini, A. (1990). Sensory and objective measurement of sandiness in dulce de leche, a typical Argentine product. Journal of Dairy Science, 73, 604-611.

Joyner, H. S. (2018). Explaining food texture through rheology. Current Opinion in Food Science, 21, 7–14.

Kirchmeier, O. (1980). Buffer capacities and buffer equilibrium of milk. Milchwissenschaft, 35, 667-670.

Liu, Y. X., Cao, M. J., & Liu, G. M. (2019). Texture analyzers for food quality evaluation. In Evaluation Technologies for Food Quality (pp. 441-463). Woodhead Publishing.

Lucey, J. A., Hauth, B., Gorry, C. & Fox, P. F. (1993). The acid-base buffering properties of milk. Milchwissenschaft, 48, 268-272.

Lund, M. N. & Ray, C. A. (2017). Control of maillard reactions in foods: strategies and chemical mechanisms. Journal of Agricultural and Food Chemistry, 65 (23), 4537–4552.

Martinez, E., Hough, G. & Contarini, A. (1990). Sandiness prevention in dulce de leche by seeding with lactose. Journal of Dairy Science, 73 (3), 612-616.

Mezger, T. G. (2014). The rheology handbook. (4a ed.), Vicentz Network, 2014.

Navarro, A. S., Ferrero, C. & Zaritzky, N. E. (1999). Rheological characterization of dulce de leche by dynamic and steady shear measurement. Journal of Texture Studies, 30, 43–58.

Nishinari, K. & Fang, Y. (2018). Perception and measurement of food texture: Solid foods. Journal of Texture Studies, 49 (2), 160–201.

Nishinari, K., Fang, Y. & Rosenthal, A. (2019). Human oral processing and texture profile analysis parameters: bridging the gap between the sensory evaluation and the instrumental measurements. Journal of Texture Studies, 50 (5) ,369–380.

Nooshkam, M., Varidi, M. & Bashash, M. (2019). The Maillard reaction products as food-born antioxidant and antibrowning agents in model and real food systems. Food Chemistry, 275, 644–660.

Pauletti, M., Venier, A., Sabbag, N. & Stechina, D. (1990). Rheological characterization of dulce de leche, a confectionery dairy product. Journal of Dairy Science. 73 (3), 601–603.

Penci M. & Marin, M. (2016). Dulce de leche: technology, quality, and consumer aspects of the traditional milk caramel of south america. Traditional Foods, 123 – 136.

Penci, M. C., & Marín, M. A. (2016). Dulce de leche: Technology, quality, and consumer aspects of the traditional milk caramel of South America. In Traditional foods (pp. 123-136).

Pinto, A. P. E. F., & Wolfschon-Pombo, A. (1984). 5-Hidroximetilfurfural no doce de leite. Revista do Instituto de Laticínios Cândido Tostes, 39, 09-11.

Ranalli, N., Andrés, S. C. & Califano, A. N. (2011). Physicochemical and rheological characterization of dulce de leche. Journal of Texture Studies, 43 (2), 115–123.

Ranalli, N., Andrés, S. C., & Califano, A. N. (2016). Rheological Behavior of Low‐Fat Dulce De Leche with Added Xanthan Gum. Journal of Food Processing and Preservation, 41(4), 1-8.

Rao, M. A. (2013). Rheology of fluid, semisolid and solid foods: Principles and applications. (3a ed.), Springer.

Rovedo, C. O., Viollaz, P. E., & Suarez, C. (1991). The effect of pH and temperature on the rheological behavior of Dulce de leche, a typical dairy Argentine product. Journal of dairy science, 74(5), 1497-1502.

Sabioni, J. G., Pinheiro, A. J. R., Silva, D. O., Chaves, J. B. P., & Borges, A. C. (1984a). Control of lactose crystallization in “dulce de leche” by beta-D-galactosidase activity from permeabilized Kluyveromyces lactis cells. Journal of dairy science, 67(10), 2210-2215.

Sabioni, J. G., Silva, D. O., Pinheiro, A. J. R., Borges, A. C., & Chaves, J. B. P. (1984b). Control of Lactose Crystallization in “Dulce de Leche” by Kluyveromyces lactis Fermentation. Journal of Dairy Science, 67(8), 1694-1698.

Salaün, F., Mietton, B., & Gaucheron, F. (2005). Buffering capacity of dairy products. International Dairy Journal, 15(2), 95-109.

Schuck, P. (2011). Lactose Crystallization. Encyclopedia of Dairy Sciences. Oxford: Academc Press, (2a ed.), 3, 182 -185.

Skoog, D. A; Holler, F. J.; Crouch, S. R. (2016). Principles of instrumental analysis. (7a ed.), Cengage Learning.

Starowicz, M. & Zieliński, H. (2019). How maillard reaction influences sensorial properties (color, flavor and texture) of food products? Food Reviews International, 35 (8), 707–725.

Stephani, R., Francisquini, J., Perrone, Í. T., de Carvalho, A. F., & de Oliveira, L. F. C. (2019). Dulce de Leche - chemistry and processing technology. In Milk Production, Processing and Marketing (pp. 1-18). London: IntechOpen.

Stokes, J. R. & Xu, Y. (2019). Rheology of Food Materials: Impact on and Relevance in Food Processing. Reference Module in Food Science.

Tan, R. (2009). Manufacture of sweetened condensed milk and significance of lactose. In P. F. Fox & P. L. H. McSweeney (Eds.), Advanced dairy chemistry: lactose, water, salts and minor constituents. (4a ed.), 3. Thomson Science.

Van Slyke, D. D. (1922). On the measurement of buffer values and on the relationship of buffer value to the dissociation constant of the buffer and the concentration and reaction of the buffer solution. The Journal of Biological Chemistry, 52, 525–570.

Walstra, P., Geurts, T. J., Noomen, A., Jellema, A. & Van Boekel, M, A, J. S. (2001). Ciencia de la Leche y Tecnología de los Productos Lácteos. Zaragoza: Editora Acribia.

Whittier, E. O. (1929). Buffer intensities of milk and milk constituents. Journal of Biological Chemistry, 83, 79-88.

Wiley, W. J. (1935). A study of the titratable acidity of milk - II. The buffer curves of milk. Journal of Dairy Research, 6, 86-90.

Wolfschoon-Pombo, A., Böttger, D., & Lösche, K. (2012). Pufferkapazität mikrofiltrierter Magermilchkonzentrate. Chemie-Ingenieur-Technik, 84 (4),465–474.

Wolfschoon-Pombo, A. F., Spiegel, T. L. & Hernandez-Zenil, E. (2017). Buffering curves of ideal whey fractions obtained from a cascade membrane separation process. International Journal of Dairy Technology, 70 (2), 287–296.

Published

12/09/2021

How to Cite

CARNEIRO, L. C. M. .; PINTO, C. B. dos A. .; GOMES, E. R. .; PAULA, I. L. de; POMBO, A. F. W.; STEPHANI, R.; CARVALHO, A. F.; PERRONE, Ítalo. The chemistry and technology of dulce de leche: a review . Research, Society and Development, [S. l.], v. 10, n. 11, p. e155101119408, 2021. DOI: 10.33448/rsd-v10i11.19408. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/19408. Acesso em: 25 apr. 2024.

Issue

Section

Agrarian and Biological Sciences