Relation between the Epoxy Resin Curing and the Mechanical Properties of the Composite Reinforced with Aramid/Glass
DOI:
https://doi.org/10.33448/rsd-v10i14.22393Keywords:
Curing cycle; Curing cycle, Epoxy Resin, Tensile, Impact, FTIR Spectroscopy.; Epoxy resin; Tensile; Impact; FTIR spectroscopy.Abstract
DGEBA has a widespread use in the manufacture of polymer composites to obtain different elements of structural engineering. The mechanical properties can be predicted by the physical-chemical knowledge of the processing conditions of the resin components, and of their storage and handling conditions. This study aimed to characterize the functional groups, as well as the curing behavior of a batch of resin with different times of storage and storage control, using FTIR spectroscopy. The resin was used in the matrix of the composites with textile reinforcement, for which the mechanical behavior was examined through tensile and impact tests. It was noticed that the degradation effect in the polymer structure causes a reduction in the tensile strength and in the impact energy of the composite.
References
Baig, Z., Akram, N., Zia, K. M., Saeed, M., Khosa, M. K., Ali, L., Saleem, S. (2020), Influence of amine-terminated additives on thermal and mechanical properties of diglycidyl ether of bisphenol A (DGEBA) cured epoxy. J. Appl. Polym. Sci., 137, 48404. doi: https://doi.org/10.1002/app.48404
Banerjee, S., & Sankar, B. V. (2014). Mechanical properties of hybrid composites using finite element method based micromechanics. Composites Part B: Engineering, 58, 318-327.
Block, C., Van Mele, B., Van Puyvelde, P., & Van Assche, G. (2013). Time–temperature-transformation (TTT) and temperature–conversion-transformation (TxT) cure diagrams by RheoDSC: Combined rheometry and calorimetry on an epoxy-amine thermoset. Reactive and Functional Polymers, 73(2), 332-339.
Cakić, S. M., Ristić, I. S., Jašo, V. M., Radičević, R. Ž., Ilić, O. Z., & Simendić, J. K. (2012). Investigation of the curing kinetics of alkyd–melamine–epoxy resin system. Progress in organic coatings, 73(4), 415-424.
Coates, J. (2000). Interpretation of infrared spectra, a practical approach, In: Meyer, R. A. Encyclopedia of analytical chemistry, New York: John Wiley.
Cozza, R. C., & Verma, V. (2020). Evaluation of fracture toughness of epoxy polymer composite incorporating micro/nano silica, rubber and CNTs. Polímeros, 30.
Ghaemi, M., & Hasanpour, S. A. (2008). Study of the cure reaction of DGEBA/ABS blend in the presence of aromatic diamine.
González, M. G., Cabanelas, J. C., & Baselga, J. (2012). Applications of FTIR on epoxy resins-identification, monitoring the curing process, phase separation and water uptake. Infrared Spectroscopy-Materials Science, Engineering and Technology, 2, 261-284.
Hardis, R., Jessop, J. L., Peters, F. E., & Kessler, M. R. (2013). Cure kinetics characterization and monitoring of an epoxy resin using DSC, Raman spectroscopy, and DEA. Composites Part A: Applied Science and Manufacturing, 49, 100-108.
Kondyurin, A., Komar, L. A., & Svistkov, A. L. (2012). Combinatory model of curing process in epoxy composite. Composites Part B: Engineering, 43(2), 616-620.
Li, C., Fan, H., Hu, J., & Li, B. (2012). Novel silicone aliphatic amine curing agent for epoxy resin: 1, 3-Bis (2-aminoethylaminomethyl) tetramethyldisiloxane. 2. Isothermal cure, and dynamic mechanical property. Thermochimica acta, 549, 132-139.
Li, Q., Li, X., & Meng, Y. (2012). Curing of DGEBA epoxy using a phenol-terminated hyperbranched curing agent: Cure kinetics, gelation, and the TTT cure diagram. Thermochimica acta, 549, 69-80.
Lorwanishpaisarn, N., Kasemsiri, P., Srikhao, N., Son, C., Kim, S., Theerakulpisut, S., & Chindaprasirt, P. (2021). Carbon fiber/epoxy vitrimer composite patch cured with bio‐based curing agents for one‐step repair metallic sheet and its recyclability. Journal of Applied Polymer Science, 138(47), 51406.
Meenakshi, K. S., Sudhan, E. P. J., Kumar, S. A., & Umapathy, M. J. (2012). Development of dimethylsiloxane based tetraglycidyl epoxy nanocomposites for high performance, aerospace and advanced engineering applications. Progress in Organic Coatings, 74(1), 19-24.
Menezes, G. W., Monteiro, S. N., D Almeida, J. R. M., & Nogueira Neto, H. D. S. (2013). Análise térmica da resina epóxi DGEBA/TETA para formulações diferentes da razão estequiométrica. Tecnologia em Metalurgia, Materiais e Mineração, 1(1), 12-16.
Merad, L., Cochez, M., Margueron, S., Jauchem, F., Ferriol, M., Benyoucef, B., & Bourson, P. (2007). In-situ monitoring of the curing of epoxy resins by Raman spectroscopy. In New Achievements in Materials and Environmental Sciences Names (pp. 155-158). EDP Sciences.
Neto, F. L., & Pardini, L. C. (2016). Compósitos estruturais: ciência e tecnologia. Editora Blucher.
Oliveira, M. S., da Luz, F. S., Pereira, A. C., Demosthenes, L. C. D. C., Nascimento, L. F. C., & Monteiro, S. N. (2020). Tensile Properties of Epoxy Matrix Reinforced with Fique Fabric. In Materials Science Forum (Vol. 1012, pp. 14-19). Trans Tech Publications Ltd.
Okoro, C., Mohammed, Z., Jeelani, S., & Rangari, V. (2021). Plasticizing effect of biodegradable dipropylene glycol bibenzoate and epoxidized linseed oil on diglycidyl ether of bisphenol A based epoxy resin. Journal of Applied Polymer Science, 138(28), 50661.
Pereira A. S. et al. (2018). Metodologia da pesquisa científica. [free e-book]. Santa Maria/RS. Ed. UAB/NTE/UFSM.
Ramesh, M., Palanikumar, K., & Reddy, K. H. (2013). Mechanical property evaluation of sisal–jute–glass fiber reinforced polyester composites. Composites Part B: Engineering, 48, 1-9.
Rezende, M. C., Costa, M. L., & Botelho, E. C. (2011). Compósitos estruturais: tecnologia e prática. São Paulo: Artliber, 34-37.
Tudorachi, N., & Mustata, F. (2020). Curing and thermal degradation of diglycidyl ether of bisphenol A epoxy resin crosslinked with natural hydroxy acids as environmentally friendly hardeners. Arabian Journal of Chemistry, 13(1), 671-682.
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Copyright (c) 2021 Silvio Leonardo Valença; Eliana Midori Sussuchi; Sandro Griza; Gabriela Oliveira Valença; Cochiran Pereira dos Santos
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