Adsorption of methyl orange dye onto activated carbon prepared from cupuaçu shell

Authors

DOI:

https://doi.org/10.33448/rsd-v12i14.44394

Keywords:

Residual biomass; Adsorbent; Textile dye; Kinetic models.

Abstract

The contamination of water resources by synthetic chemical substances, such as textile dyes, represents a serious environmental problem, as many of these compounds are toxic and can cause damage to the environment and human health. This work aimed to evaluate the efficiency of activated carbon obtained from cupuaçu shell in the adsorption process of methyl orange dye. The adsorbent was prepared by chemical activation using 85% phosphoric acid followed by carbonization at 500 oC for 60 minutes. The batch adsorption tests were performed using activated carbon with different dosage diluted in a dye solution at 10 mg/L. The kinetic tests results showed that equilibrium was achieved after 10 minutes, with almost 100% removal, maximum adsorption capacity of 9.50 mg/g (mads = 50 mg) and 19.70 mg/g (mads = 25 mg). The experimental data were fitted to pseudo-first-order, pseudo-second-order and intraparticle diffusion kinetic models, with the pseudo-second-order being the one that best described the process, resulting in values closer to the maximum adsorbed capacity at equilibrium, experimental and calculated. In this way, activated carbon from cupuaçu shell showed excellent potential in methyl orange adsorption studies, becoming a promising alternative in the remediation of organic pollutants.

Author Biographies

Mayra Paula de Souza e Sousa, Universidade Federal do Amazonas

Engenharia Química pela Universidade Federal do Amazonas (2017- 2023) com Duplo diploma, através do programa BRAFITEC (Brasil França Engenharia Tecnologia), em Engenharia Quimica, com especialização em Engenharia de Processos, pela Ecole Nationale Supérieure de Chimie de Clermont-Ferrand (atual SIGMA Clermont), na França. Atuou no projeto de desenvolvimento tecnológico intitulado: Projeto e construção de um extrator solar de óleos essenciais de plantas aromáticas e medicinais da Amazônia, onde foi bolsista (2018-2019). Participou como Apoio Técnico do projeto Desempenho do Bioadsorvente obtido de resíduos amazônicos no processo de descontaminação do Rio Negro por derivados de petróleo, como bolsista pela Fundação de Amparo à Pesquisa do Estado do Amazonas (2022-2023). Atuou como estagiária gerencial na empresa Procter Gamble (2022 - 2023).

Cristiane Daliassi Ramos de Souza, Universidade Federal do Amazonas

Possui graduação em Engenharia Química pela Universidade Federal do Ceará, mestrado em Engenharia Química pela Universidade Federal do Rio Grande do Norte e doutorado em Química (biocombustíveis) pela Universidade Federal do Amazonas. Atualmente é professora Associada do curso de Engenharia Química da Universidade Federal do Amazonas e pesquisadora do Centro de Desenvolvimento Energético Amazônico (CDEAM). Tem experiência nas áreas de Química Analítica e Engenharia Química, com ênfase em adsorção, biocombustíveis, catalisadores mesoporosos, remediação de derramamentos de petróleo e aproveitamento energético de biomassa

Lucas Orleam Nunes do Nascimento, Universidade Federal do Amazonas

Tem experiência na área de Engenharia química com foco em desenvolvimento de produtos naturais e indústria farmacêutica. Atualmente, tem interesses nas áres de controle e simulação de processos químicos.

Mikelle Silva de Oliveira, Universidade Federal do Amazonas

Mestrado em Ciências Ambientais, Especialização em Metodologia do Ensino da Química, Graduação em Tecnologia em Processos Químicos e Licenciatura em Química, Técnico em Química. Possui experiência na área industrial/galvanoplastia e gerenciamento em laboratórios de ensino/pesquisa, atualmente é Servidora Pública Federal da UFAM no cargo de técnica de laboratório/área: química, lotada no Departamento de Engenharia Química.

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Published

17/12/2023

How to Cite

SOUSA, M. P. de S. e .; SOUZA, C. D. R. de .; NASCIMENTO, L. O. N. do .; OLIVEIRA, M. S. de . Adsorption of methyl orange dye onto activated carbon prepared from cupuaçu shell. Research, Society and Development, [S. l.], v. 12, n. 14, p. e17121444394, 2023. DOI: 10.33448/rsd-v12i14.44394. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/44394. Acesso em: 25 dec. 2024.

Issue

Vol. 12 No. 14

Section

Engineerings

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Copyright (c) 2023 Mayra Paula de Souza e Sousa; Cristiane Daliassi Ramos de Souza; Lucas Orleam Nunes do Nascimento; Mikelle Silva de Oliveira

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