Methylene Blue Biosorption using sawdust of the Apuleia Leiocarpa genus
DOI:
https://doi.org/10.33448/rsd-v9i7.4768Keywords:
Biomass; Adsorption; Dye; Packed bed.Abstract
The adsorption is promising technique for dyes removal from textile effluents, among them methylene blue (AM). This technique is even more attractive when using low cost materials such as sawdust (PS) as adsorbents. The aim of this work was to study the use of sawdust powder of the Apuleia Leiocarpa as adsorbent material in the methylene blue (AM) biosorption from textile effluents. Experimental tests were carried out in stirred tank to determine the equilibrium isotherm and the kinetics of adsorption, fitting the most usual models in literature. The fixed bed tests were conducted to obtain the rupture curves, which correlate the dye concentration with time, under different conditions of initial solution concentration and feed flow rate. The results showed that the equilibrium isotherm was favorable, indicating the PS as a good adsorbent, with a maximum adsorption capacity of 61.8 mg/g. The Yan model satisfactorily represented the adsorption process in the fixed bed. The higher adsorption capacity occurred working with a concentrate solution at the lower feed flow rate, which presented a higher useful percentage of bed, indicating the PS as good adsorbent to remove AM from liquid effluents.
References
Abdulhameed, A.S., Mohammad, A.T., Jawad, A.H. (2019). Modeling and mechanism of reactive orange 16 dye adsorption by chitosan-glyoxal/TiO2 nanocomposite: application of response surface methodology. Desalin Water Treat., 164, 346–360.
Agarwal, S., Tyagi, I., Gupta, V.K., Ghasemi, N., Shahivand, M. & Ghasemi, M. (2016). Kinetics, equilibrium studies and thermodynamics of methylene blue adsorption on Ephedra strobilacea saw dust and modified using phosphoric acid and zinc chloride. Journal of Molecular Liquids, 218, 208-218.
Aichour, A., Zaghouane-Boudiaf, H., Zuki, F.B.M.,Aroua, M.K. & Ibbora, C.V. (2019). Low-cost, biodegradable and highly effective adsorbents for batch and column fixed bed adsorption processes of methylene blue. Journal of Environmental Chemical Engineering, 7(5), 103409.
Alfredo, A. P. C.; Gonçalves, G. C.; Lobo, V. S. & Montanher, S. F. (2015) Adsorção de Azul de Metileno em Casca de Batata Utilizando Sistemas em Batelada e Coluna de Leito Fixo, Rev. Virtual Quim., 7, p. 1909-1920.
Almeida, N.P. & Santos, K.G. (2020). Chemical Engineering Laboratory teaching using Project-based learning approach: gas adsorption using banana peel. Research, Society and Development, (9)3, e184932716.
Bagatini, M., Bonzanini, V. & Oliveira, E.C., (2017). Análise da qualidade da água em poços artesianos na região de Roca Sales, Vale do Taquari. Caderno pedagógico, 14(1),84-91.
Brião, G.V., Jahn, S.L., Foletto, E.L. & Dotto, G.L. (2018). Highly efficient and reusable mesoporous zeolite synthetized from a biopolymer for cationic dyes adsorption. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 556(5), 43–50.
Buthiyappan, A., Abdul, J.G. & Abdul, A. (2019). Raman Synthesis of iron oxides impregnated green adsorbent from sugarcane bagasse: Characterization and evaluation of adsorption efficiency. Journal of Environmental Management, 249(1), 109323.
Charola, S., Yadav, R., Das, P. & Maiti, S. (2018). Fixed-bed adsorption of Reactive Orange 84 dye onto activated carbon prepared from empty cotton flower agro-waste. Sustainable Environment Research, 28(6), 298-308.
Colombo, A. (2013) Biossorção dos Íons Cádmio e Chumbo pela Casca de Soja. Dissertação de Mestrado na Universidade Estadual do Oeste do Paraná, Toledo – PR.
Guimarães, B.; Silva, J. T. T.; Santos, K. G. & Neto, J. L. V. (2020). Sequencing of unit operations for integral and sustainable peanut processing. Research, Society and Development, 9(6), e67963449.
Ho, Y. & Mckay, G. (1998), Sorption of dye from aqueous solution by peat. Chemical Engineering Journal, 70, 115–124.
Ismail, M.I., Fadzil, M.S.M., Rosmadi, N.N.F., Razali, N. R. A. M. & Mohamad Daud, A.R. (2019) Acid treated corn stalk adsorbent for removal of alizarin yellow dye in wastewater. Journal of Physics: Conference Series, 1349, 012105.
Jawad, A. H., Abdulhameed, A.S. & Mastuli, M.S. (2020) Acid-factionalized biomass material for methylene blue dye removal: a comprehensive adsorption and mechanism study. Journal of Taibah University for Science, 14(1), 305-313.
Jorge, I. R.; Tavares, F. P. & Santos, K. G. (2015), Remoção do corante azul de metileno no tratamento de efluentes por adsorção em bagaço de cana de açúcar. In: Anais do XXXVII Congresso Brasileiro de Sistemas Particulados - ENEMP, São Carlos. v.2.
Lovatel, Q.C., Menegatti, R.D., Oliveira, M.P., Navroski, M.C., Smiderle, O.J., Souza, A.G. & Oliveira, L.M. (2019). Biometria e qualidade fisiológica de sementes de diferentes matrizes de apuleia Leiocarpa (Vogel) J.F. MACBR. In: Sementes: Ciência, Tecnologia e Inovação. Capitulo 2, Organizador Igor Luiz Vieira de Lima Santos. – Ponta Grossa, PR: Atena Editora.
Mu, B. &, Wang, A. (2016). Adsorption of dyes onto palygorskite and its composites: a review. J. Environ. Chem. Eng., 4(1), 1274–1294.
Müller, L. C. (2016) Tratamento de água para abastecimento utilizando elementos filtrantes de madeira. Dissertação de Mestrado na Universidade Federal de Santa Catarina, Florianópolis.
Salem, I.A., Fayed, T.A. & El-Nahass, M.N. (2018). Mohamed Dawood A Comparative Study for Adsorption of Methylene Blue Dye from Wastewater on to Three Different Types of Rice Ash. Journal of Pharmaceutical and Applied Chemistry, 4(2), 99-107.
Sotiles, A. R. (2017). Estudo de diferentes tratamentos da caulinita para possível aplicação como adsorvente do corante têxtil C.I. Reactive Blue 203. Dissertação de Mestrado na Universidade Tecnológica Federal do Paraná, Paraná.
Upendar, G., Biswas, G., Adhikari, K. & Dutta, S. (2017). Adsorptive removal of methylene blue dye from simulated wastewater using shale: Experiment and modelling. J. Indian Chem. Soc., 94, 1-12.
Zhang, W.; Dong, L.; Yan, H.; Li, H.; Jiang, Z.; Kan, X.; Yang, H.; Li, A. & Cheng, R. (2011). Removal of Methylene Blue From Aqueous Solutions by Straw Based Adsorbent in a Fixed-bed Column. Chemical Enginnering Journal, 173, 429-433.
Zhou, Y., Lu, J., Zhou, Y & Liu, Y. (2019). Recent Advances for Dyes Removal Using Novel Adsorbents: A Review. Environ Pollut., 252, 352-365.
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