Study of the influence of the aluminum source (acetate or sulfate) on the synthesis of the ceramic membrane and applications of emulsion oil water: use and reuse




Aluminum sulfate; Aluminum acetate; Ceramic membranes; Emulsion oil/water; Reuse.


The objective of this work was to prepare ceramic membranes and to evaluate the effect of the raw material on the ceramic membrane and on the efficiency of the emulsion separation oil/water. The ceramic membranes were manufactured using the uniaxial dry compaction method, from the thermal decomposition of aluminum sulfate or aluminum acetate, to evaluate the effect of the raw material (aluminum acetate or aluminum sulfate) on the efficiency in the emulsion oil/water separation. Ceramic membranes were characterized by measurements of X-ray diffraction patterns, scanning electron microscopy, mechanical strength, bubble point and water flow. In this study, membranes were produced with different characteristics. The values found for the permeate for the A1 membrane were 9.20 mg / L due to characteristics such as porosity and mechanical strength (44.63 % and 1.3 MPa), while the values A2 membrane was 6.52 mg / L, 18.86 % and 6.7 MPa. In conclusion, the membranes prepared are effective in removing the oil from the oily waste water. According to the results, the treatment of oil-water emulsions by microfiltration facilitates a significant reduction in the concentration of permeate oil.


Ashaghi, K. S., Ebrahimi, M., & Czermak, P. (2007). Ceramic Ultra- and Nanofiltration Membranes for Oilfield Produced Water Treatment: A Mini Review. Open Environmental Sciences, 1, 1-8. https://10.2174/1876325100701010001

Barbosa, A. S., Barbosa, A. S., & Rodrigues, M. G. F. (2019). Influence of the methodology on the formation of zeolite membranes MCM-22 for the oil/water emulsion separation. Cerâmica, 65, 531-540.

Barbosa, A. S., Barbosa, A. S., Barbosa, T. L. A., & Rodrigues, M. G. F. (2018). Synthesis of zeolite membrane (NaY/alumina): Effect of precursor of ceramic support and its application in the process of oil–water separation. Separation and Purification Technology, 200, 141–154.

Barbosa, T. L. A., Silva, F. M. N., Barbosa, A. S., Lima, E. G., & Rodrigues, M. G. F. (2020). Synthesis and application of a composite NaA zeolite/gamma-alumina membrane for oil-water separation process. Cerâmica, 66, 137-144.

Bayat, A., Mahdavi, H. R., Kazemimoghaddam, M., & Mohammadi, T. (2016). Preparation and characterization of γ-alumina ceramic ultrafiltration membranes for pretreatment of oily wastewater. Desalination and Water Treatment, 57, 24322-24332.

Bilstad, T., & Espedal, E. (1996). Membrane separation of produced water. Water Science & Technology, 34, 239–246.

Burggraaf, A. J., & Cot, L. (1996). Fundamentals of Inorganic Membranes Science and Technology, series 4, 1st Ed., Elsevier Science B. V, Amsterdam.

Busca, G. (2014). Structural, Surface, and Properties of Aluminas. Chapter three. Advances in Catalysis, 57, 319-404.

Çakmakce, M., Kayaalp, N., & Koyuncu, I. (2008). Desalination of produced water from oil production fields by membrane processes. Desalination, 222, 176–186.

Ebrahimi, M., Kerker, S., Schmitz, O., & Czermak, P. (2018). Evaluation of the fouling potential of ceramic membrane configurations designed for the treatment of oilfield produced water. Separation Science and Technology, 53, 349-363.

Evans, A., Strezov, V., & Evans, T. J. (2009). Assessment of sustainability indicators for renewable energy technologies. Renewable and Sustainable Energy Reviews, 13, 1082–1088. https://doi:10.1016/j.rser.2008.03.008

Gallucci, F., Basile, A., & Hai, F. I. (2011). In: Membranes for membrane reactors: preparation, optimization and selection, Wiley, Chichester, UK.

He, Y., & Jiang, Z-W. (2008). Technology review: Treating oilfield wastewater. Filtration & Separation, 45, 14–16.

Li, Y. S., Yan, L., Xiang, C. B., & Hong, L. J. (2006). Treatment of oily wastewater by organic–inorganic composite tubular ultrafiltration (UF) membranes. Desalination, 196, 76–83.

Lodungi, J. F., Alfred, D. B., Khirulthzam, A. F. M., Binti Adnan, F. F. R., & Tellichandran, S. (2016). A Review in Oil Exploration and Production Waste Discharges According to Legislative and Waste Management Practices Perspective in Malaysia. International Journal of Waste Resources, 7, 1-8. https://doi:10.4172/2252-5211.1000260

Madaeni, S. S., Ahmadi Monfared, H., Vatanpour, V., Arabi Shamsabadi, A., Salehi, E., Daraei, P., Laki, S., & Khatami, S. M. (2012). Coke removal from petrochemical oily wastewater using γ-Al2O3 based ceramic microfiltration membrane. Desalination, 293 87–93.

Padaki, M., Murali, R. S., Abdullah, M. S., Misdan, N., Moslehyani, A., Kassim, M. A., Hilal, N., & Ismail, A. F. (2015). Membrane technology enhancement in oil-water separation: A review. Desalination, 357, 197–207.

Pelovski, Y., Pietkova, W., Gruncharov, I., Pacewska, B., & Pysiak, J. (1992). The thermal decomposition of aluminum sulfate in different gas phase environments. Thermochimica Acta, 205, 219-224.

Qi, H., Niu, S., Jiang, X., & Xu, N. (2013). Enhanced performance of a macroporous ceramic support for nanofiltration by using α-Al2O3 with narrow size distribution. Ceramics International, 39, 2463–2471.

Samaei, S. M., Gato-Trinidad, S., & Altaee, A. (2018). The application of pressure-driven ceramic membrane technology for the treatment of industrial wastewaters – A review. Separation and Purification Technology, 200, 198-200.

Santos, R. C. R., Pinheiro, A. N., Leite, E. R., Freire, V. R. N., Longhinotti, E., & Valentini, A. (2015). Simple synthesis of Al2O3 sphere composite from hybrid process with improved thermal stability for catalytic applications. Materials Chemistry and Physics, 160, 119-130.

Sato, T., Ikoma, S., & Ozawa, F. (1984). Thermal decomposition of organic basic aluminium salts—formate and acetate. Thermochimica Acta, 75, 129-137.

Sikdar, S. K., Criscuoli, A., in: Figoli & A. Criscuoli (Eds.) (2017). Sustainable Membrane Technology for Water and Wastewater Treatment, Springer Nature, Singapore Pte Ltd., 1-21.

Singh, R. (2015). Membrane Technology and Engineering for Water Purification. Second Edition, Application, Systems Design and Operation, Butterworth Heinemann, Oxford, UK, 81-178.

Suresh, K., Pugazhenthi, G., & Uppaluri, R. (2016). Fly Ash Based Ceramic Microfiltration Membranes for Oil-water Emulsion Treatment: Parametric Optimization using Response Surface Methodology. Journal of Water Process Engineering, 13, 27-43.

Wegmann, M., Michen, B., & Graule, T. (2008). Nanostructured surface modification of microporous ceramics for efficient virus filtration. Journal of the European Ceramic Society, 28:1603-1612.

Zaidi, A., Simms, K., & Kok, S. (1992). The Use of Micro/Ultrafiltration for the Removal of Oil and Suspended Solids from Oilfield Brines. Water Science & Technology, 25, 163–176.

Zhong, J., Sun, X., & Wang, C. (2003). Treatment of oily wastewater produced from refinery processes using flocculation and ceramic membrane filtration. Separation and Purification Technology, 32, 93-98.

Zhong, Z., Xing, W., & Zhang, B. (2013). Fabrication of ceramic membranes with controllable surface roughness and their applications in oil/water separation. Ceramics International, 39, 4355–4361.




How to Cite

BARBOSA, A. dos S.; BARBOSA, A. dos S. .; RODRIGUES, M. G. F. Study of the influence of the aluminum source (acetate or sulfate) on the synthesis of the ceramic membrane and applications of emulsion oil water: use and reuse. Research, Society and Development, [S. l.], v. 10, n. 13, p. e75101321023, 2021. DOI: 10.33448/rsd-v10i13.21023. Disponível em: Acesso em: 6 dec. 2021.