Selective flocculation and floc-flotation of iron bearing mineral slimes

Authors

DOI:

https://doi.org/10.33448/rsd-v11i5.28289

Keywords:

Selective flocculation; Iron ore; Flotation; Ultrafine.

Abstract

The mineral processing of friable iron ores usually generates ultrafine (smaller than 15 µm) particles, normally called slimes, which usually have a high iron grade and are usually disposed into tailings dam. The traditional mineral process techniques for iron ore do not work efficiently with ultrafines; however, selective flocculation is an alternative to concentrate that fraction. The physical-chemical treatment of iron ore slime was studied here, on a bench scale, based on the scientific foundations of selective flocculation and flotation. Samples of slimes from two Brazilian iron ore processing plants (CEII and VGII) and industrial process waters were used in the tests. Complexometric titration of calcium and magnesium indicated that the process waters were adequate for selective flocculation. Only selective flocculation, even under optimum conditions, did not achieve good results. However, its use prior to flotation led to promising results. The VGII sample has stood out, for which the final concentrate achieved 60.1 % of Fe, the mass recovery was 64.5 % and 13.5 % of Fe in the tailing, resulting selectivity index of 6.58, only with one stage of selective flocculation and one stage of flotation.

References

Araujo, A. C., Viana, P. R. M., & Peres, A. E. C. (2005). Reagents in iron ores flotation. Minerals Engineering, 18. pp. 219-222.

Arol, A. I., Iwasaki, I. (2003). Effect of sodium silicate on flocculation of hematite with starch in the presence of calcium. Separation Science and Technology, 38, 3, pp. 647-659.

Chen, T., Su, T., Zhang, Y., & Hu, P. (2 016). Selective Flocculation Enhanced Magnetic Separation of Ultrafine Disseminated Magnetite Ores. Minerals, 6, 86.

Colombo, A. F. (1980). Selective flocculation and flotation of iron bearing minerals: Fine Particles Processing. New York: AIME.

Drzymala, J., & Fuerstenau, D. W. (1981). Selective flocculation of hematite in the hematite-quartz-ferric ion-polyacrylic acid system - Part 1, Activation and Deactivation of Quartz, International Journal of Mineral Processing, 8. pp. 265–277.

Gaudin, A. M., Groh, J. O., & Henderson, H. B. (1931). Effect of particle size on flotation, AIME, Tech. Publ., 414. pp. 3-23.

Haselhuhn, H. J.; Carlson, J. J., & Kawatra, S. K. (2012). Water chemistry analysis of an industrial selective flocculation dispersion hematite ore concentrator plant. International Journal of Mineral Processing, 102-103. pp. 99-106.

Haselhuhn, H. J., & Kawatra, K. (2015). Effects of Water Chemistry on Hematite Selective Flocculation and Dispersion. Mineral Processing & Extractive Metallurgy Review, 36. pp. 305-309.

Krishnan, S.V., & Iwasaki, I. (1983). Sodium silicate as a dispersant in selective flocculation of iron ores. Trans. SME-AIME, 272. pp. 1984–1988.

Kumar, R., & Mandre, N. R. (2016). Beneficiation of iron ore slimes using a natural polymer by selective flocculation process. International Seminar on Mineral Processing Technology. Pune, India. pp. 421-428.

Luz, J. A. M. (2015). Encyclopedia of Iron, Steel, and Their Alloys: Flotation of Iron Ore. Bosa Roca: Taylor & Francis Group.

Ma, M. (2012). The dispersive effect of sodium hexametaphosphate on kaolinite in saline water. Clays and Clays minerals, 60. pp. 405-410.

Mukherjee, A. K., Thella, J. S., Makhija, D., Patra, A. S., Manna, M., & Ghosh, T. K. (201 5). Process to Recover Iron Values from High-Alumina Indian Iron Ore Slime – a Bench-Scale Study. Mineral Processing & Extractive Metallurgy Review, 36. pp. 39-44.

Pradip, Ravishankar, S. A., Sankar, T. A. P., & Khosla, N. K. (1993). Beneficiation Studies on Alumina-Rich Indian Iron Ore Slimes using Selective Dispersants, Flocculants and Flotation Collectors. XVIII International Mineral Processing Congress, Sydney, Australia, pp. 1289-1294.

Pradip, Rai, B., Waghmare, U. V., & Tammishetti, V. (2013). Processing of Alumina-Rich Iron Ore Slimes: Is the Selective Dispersion Flocculation Flotation the Solution.... Transactions of the Indian Institute of Metals, 66, 5-6. pp. 447-456.

Ravishankar, S. A., Pradip, & Khosla, N. K. (1995). Selective flocculation of iron oxide from its synthetic mixtures with clays: a comparison of polyaclylic acid and starch polymers. International Journal of Mineral Processing, 43, pp. 235-247.

Roy, S. (2009). Recovery Improvement of Fine Iron Ore Particles by Multi Gravity Separation. The Open Mineral Processing Journal, 2, pp. 17-30.

Singh, B. P., & Singh, R. (1997). Investigation on the Effect of Ultrasonic Pretreatment on Selective Separation of Iron Values from Iron Ore Tailings by Flocculation. Separation Science and Technology, 32, 5. Pp. 993-1002.

Sahoo, H., Rath, S. S., Rao, D. S., Mishra, B. K., & Das, B. (2016). Role of silica and alumina content in the flotation of iron ores. International Journal of Mineral Processing, 148, pp. 83-91.

Song, S., Lopez-Valdivieso, A. (2002). Parametric aspect of hydrophobic flocculation technology. Mineral Processing and Extractive Metallurgy Review, 23, 2, pp. 101-127.

Subramanian, S., & Natarajan, K. A. (1990). Flocculation, filtration and selective flocculation studies on hematite ore fines using starch. Minerals Engineering, 4. pp. 587-598.

Tammishetti, V., Joshi, K., Rai, B., & Pradip. (2012). Selective Dispersion – Flocculation of Alumina Rich Iron Ore Slimes. International Mineral Processing Congress, 26. pp. 24-28.

Tammishetti, V., Kumar, D., Rai, B., Pradip, Shukla, V., Patra, A. S., Hakraborty, D. P., & Kumar, A. (2017). Selective Flocculation of Iron Ore Slimes: Results of Successful Pilot Plant Trials at Tata Steel, Noamundi. Transactions of the Indian Institute of Metals, 70, 2, pp. 411-419.

Weissenborn, P.K., Warren, L.J., & Dunn, J. L. (1994). Optimizations of Selective Flocculation of Ultrafine Iron Ore. International Journal of Mineral Processing, 42, pp. 191-213.

Weissenborn, P.K., Warren, L.J., & Dunn, J. L. (1995). Selective flocculation of ultrafine iron ore. Colloids and Surfaces A: Physcochemical and Engineering Aspects, pp. 11-27.

Downloads

Published

12/04/2022

How to Cite

BRETAS, P. L.; RODRIGUES, O. M. S.; LUZ, J. A. M. da . Selective flocculation and floc-flotation of iron bearing mineral slimes. Research, Society and Development, [S. l.], v. 11, n. 5, p. e45011528289, 2022. DOI: 10.33448/rsd-v11i5.28289. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/28289. Acesso em: 24 nov. 2024.

Issue

Section

Engineerings