Acetato de celulosa obtenido de la madera de Schizolobium parahyba (vell.) blake

Autores/as

DOI:

https://doi.org/10.33448/rsd-v10i12.20761

Palabras clave:

despulpado con acetosolve; Despulpado con acetosolve; acetato de celulosa; Acetato de celulosa; DMA; membrana; Membrana; Schizolobium parahyba; Schizolobium parahyba.

Resumen

Actualmente, los polímeros no biodegradables se producen a gran escala y causan varios problemas ambientales, principalmente debido a su baja degradación. El acetato de celulosa es un polímero no tóxico, poco inflamable y de bajo costo, que representa una alta importancia ambiental. El objetivo de este trabajo fue sintetizar membranas de acetato de celulosa a partir de madera de Schizolobium parahyba (guapuruvu) con tamaños de partícula de 20 y 60 mesh. Los materiales se sometieron a pulpa, blanqueo y acetilación con acetosolve para producir acetatos. Se analizaron los rendimientos encontrados y el grado de sustitución de acetatos. Las fibras se caracterizaron químicamente y las muestras obtenidas en cada paso de procesamiento se caracterizaron mediante FTIR. Fue posible preparar acetatos con madera de ambos tamaños de partícula. Los espectros FTIR mostraron cambios en las bandas de la muestra, lo que indica que los procesos químicos empleados fueron eficientes. El acetato de celulosa obtenido del material de malla 60 tuvo un mayor grado de sustitución (2,74 ± 0,12) en comparación con el acetato de malla 20 (2,59 ± 0,13), lo que indica que el tamaño de partícula del material influyó en la eficiencia de la reacción de acetilación. Las pruebas DMA demostraron que la membrana de malla 60 tiene mayor flexibilidad y transparencia en comparación con la membrana de malla 20.

Biografía del autor/a

Leticia Sant'Anna Allesi, Foundation for Research Support of the State of São Paulo

Graduated in Forestry Engineering from the Federal University of São Carlos, Sorocaba campus (2016) with a sandwich period at the University of Montana. He has experience in the area of ​​Forest Resources and Forest Engineering. He holds a master's degree in Planning and Use of Renewable Resources from the Federal University of São Carlos, Sorocaba campus, where he developed research on cellulose acetate (2019). He currently works at the Foundation for Research Support of the State of São Paulo - FAPESP, in the Audit and Internal Inspection sector of the Comptroller General.

Graduated in Forestry Engineering from the Federal University of São Carlos, Sorocaba campus (2016) with a sandwich period at the University of Montana. He has experience in the area of ​​Forest Resources and Forest Engineering. He holds a master's degree in Planning and Use of Renewable Resources from the Federal University of São Carlos, Sorocaba campus, where he developed research on cellulose acetate (2019). He currently works at the Foundation for Research Support of the State of São Paulo- FAPESP, in the Audit and Internal Inspection sector of the Comptroller General.

Joelen Osmari da Silva, Universidade Federal de São Carlos

Graduated in Polymer Technology from the Faculty of Technology of Sorocaba (FATEC-SO), Master in Materials Science from the Federal University of São Carlos (UFSCar), where he worked with the synthesis of cellulose acetate from sugarcane bagasse for application as biomaterials. She is currently a PhD student in Materials Science at the Federal University of São Carlos (UFSCar), where she works in research related to the development of hydrogels for agricultural applications. Member of the Materials Research Group Lignocellulosics (GPML) from the Federal University of São Carlos (UFSCar) Campus Sorocaba. Operates in the areas of Polymers, including: lignocellulosic materials, polymers from renewable sources and biomaterials, in particular, cellulose and its derivatives and hydrogels.

Franciane Andrade de Pádua, Universidade Federal de São Carlos

Graduated in Forest Engineering from the Federal University of Lavras (2001), Master in Forest Engineering from the Federal University of Lavras (2004) and Ph.D. in Wood Science and Technology from the Federal University of Lavras (2009). She is currently a professor on the permanent staff of the Forest Engineering course at the Federal University of São Carlos - Sorocaba campus. He was President of the Brazilian Society of Science and Technology of Madeira (management 2017-2019). He has experience in the area of ​​Forest Resources and Forest Engineering, with an emphasis on Forest Biomass Quality, acting on the following topics: Waste, evaluation and destructive and non-destructive wood sampling.

Vagner Roberto Botaro, Universidade Federal de São Carlos

Graduated in Bachelor of Chemistry with technological attributions from the University of São Paulo (1987), Master in Physical Chemistry from the University of São Paulo (1992) and Ph.D. in Physical Chemistry from the University of São Paulo (1996). The postdoctoral research was carried out at the École Française de Paeterie et des Insdutries Graphiques ? Grenoble/Fr in the group of natural polymeric materials. He is currently an associate professor - Campus Sorocaba and Productivity Researcher at CNpq. He has experience in Chemistry, with an emphasis on Organic Physical Chemistry, working mainly on the following topics: Composite materials, cellulose, modification of polysaccharides, lignin, pulping processes, production of gels derived from polysaccharides, and use of vegetable fibers in composite materials.

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Publicado

02/10/2021

Cómo citar

ALLESI, L. S.; SILVA, J. O. da; PÁDUA, F. A. de; BOTARO, V. R. Acetato de celulosa obtenido de la madera de Schizolobium parahyba (vell.) blake. Research, Society and Development, [S. l.], v. 10, n. 12, p. e584101220761, 2021. DOI: 10.33448/rsd-v10i12.20761. Disponível em: https://rsdjournal.org/index.php/rsd/article/view/20761. Acesso em: 26 dic. 2024.

Número

Vol. 10 Núm. 12

Sección

Ingenierías

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Derechos de autor 2021 Leticia Sant'Anna Allesi; Joelen Osmari da Silva; Franciane Andrade de Pádua; Vagner Roberto Botaro

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