Influencia del molino vibratorio en las propiedades del ZnO procesado por molienda de alta energía
DOI:
https://doi.org/10.33448/rsd-v10i12.20855Palabras clave:
Molienda de Alta Energia; Nanopartículas; Óxido de Zinc; Refinamiento Rietveld.Resumen
Este trabajo evalúa cómo la molienda de bolas de alta energía (MAE) en un molino agitador influye en las propiedades ópticas, físicas y microestructurales del ZnO. El procedimiento también combina la inclusión de Fe del medio de molienda con la reducción del tamaño de las partículas. El ZnO fue molido durante 1, 2, 3, 4 y 5 h, lo que resultó en una reducción del tamaño de las partículas hasta la escala nanométrica, con un tamaño medio en torno a los 50 nm, y a una reducción del tamaño de los cristalitos tres veces mayor cuando se procesó a partir de las 4 h. La molienda demostró ser un proceso eficaz para obtener nanopartículas con un tiempo de procesamiento increíblemente corto y cambió la morfología de las partículas de formas aleatorias hasta esféricas. Los resultados también indican que el procesamiento amplió progresivamente la estructura hexagonal del ZnO debido a la tensión impuesta y a la inclusión de Fe, lo que puede ayudar a disminuir el bandgap y a reducir la tasa de recombinación de los pares electrón-hueco, mejorando la actividad de fotocatálisis. Los resultados ópticos mostraron que no apareció ninguna banda adicional y una disminución del bandgap de 3,37 a 3,21 eV. MAE también condujo a un aumento del valor c de 5,2076 a 5,2112 Å, que es uno de los factores más importantes para mejorar la actividad antibacteriana. El HEBM ha demostrado ser un proceso adecuado para la obtención de nanopartículas de ZnO con propiedades útiles para diversas aplicaciones.
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Derechos de autor 2021 Ana Gabriela Storion; Eliria Maria de Jesus Agnolon Pallone; Tania Regina Giraldi; Sylma Carvalho Maestrelli
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