Spectrometric Determination of Sodium, Potassium, Calcium, Magnesium, Phosphorus and Sulfur in Soy Biodiesel
DOI:
https://doi.org/10.33448/rsd-v11i10.32495Keywords:
Biodiesel; Spectrometry; Biodiesel Specification; Metals; Ametals.Abstract
Biodiesel is considered a renewable fuel produced from vegetable oils or animal fats and is used in vehicles equipped with diesel cycle engines. This fuel was introduced in the Brazilian energy matrix through law 11.097/05, assigning to the National Agency of Petroleum, Natural Gas and Biofuel (ANP) the specifications for biodiesel, aiming to ensure its quality in compliance with technical standards and norms. Based on this fact, this work aimed to evaluate the sodium (Na), potassium (K), calcium (Ca), magnesium (Mg), phosphorus (P), and sulfur (S) contents in a biodiesel sample produced in the laboratory. Initially, the soybean oil was transesterified and then characterized by the parameters specific mass at 20 ºC and kinematic viscosity at 40 ºC. After this step, the determinations of the proposed elements began. For Na and K the atomic absorption technique was used, Mg, Ca, and P were determined by atomic emission with inductively coupled plasma and the S content by ultraviolet fluorescence. The values of 880 kg/m3, and 4.8 mm2/s for specific mass and viscosity, respectively, were the evidence that methyl esters were produced. The sum for sodium and potassium was 1.03 mg/kg, for calcium and magnesium was 0.22 mg/kg, phosphorus content was 5.00 mg/kg and sulfur content was 1.67 mg/kg. All the results indicate that the biodiesel produced is in accordance with ANP resolution No 45/14 for the investigated parameters.
References
ABNT NBR 15553, Biodiesel - Determinação dos teores de cálcio, magnésio, sódio, fósforo e potássio por espectrometria de emissão ótica com plasma indutivamente acoplado.
ABNT NBR 15556 Biodiesel - Determinação do teor de sódio, potássio, magnésio e cálcio por espectrometria de absorção atômica
ASTM D 4052- Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 445- Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity).
ASTM D5453-19a, Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence
Cruz, D. C. P., Castro, I. F. G., Sehwartz, R. L. da C., Campos, A. L. de B. S., Pereira, I. C. C., Vilhena, A. E. G. de., & Martelli, M. C. (2022). Avaliação das propriedades físico-químicas e do desempenho das três gerações de biodiesel através do processo de transesterificação: uma revisão. Research, Society and Development, 11(4), e23111427234. https://doi.org/10.33448/rsd-v11i4.27234
Froehner, S., Leithold, J., Fernando, L., & Júnior, L. (2016). Transesterificação De Óleos Vegetais: Caracterização Por Cromatografia Em Camada Delgada E Densidade. In Quim. Nova (Vol. 30, Issue 8).
Gonçalves, V. O., & Bortoleto, G. G. (2021). Determinação de metais em biodiesel: importância e desafios. Bioenergia Em Revista: Diálogos, 11(2236–9171), 120–138.
Hoang, A. T. (2021). Prediction of the density and viscosity of biodiesel and the influence of biodiesel properties on a diesel engine fuel supply system. Journal of Marine Engineering and Technology, 20(5), 299–311. https://doi.org/10.1080/20464177.2018.1532734
Lôbo, I. P., Luis, S., Ferreira, C., & Serpa Da Cruz, R. (2009). Biodiesel: Parâmetros De Qualidade E Métodos Analíticos. In Quim. Nova (Vol. 32, Issue 6).
Mathew, G. M., Raina, D., Narisetty, V., Kumar, V., Saran, S., Pugazhendi, A., Sindhu, R., Pandey, A., & Binod, P. (2021). Recent advances in biodiesel production: Challenges and solutions. In Science of the Total Environment (Vol. 794). Elsevier B.V. https://doi.org/10.1016/j.scitotenv.2021.148751
Nascimento, T. L. do, Maciel, M. A. M., Gurgel, H. E. D. S., Rios, M. A. S., & Bertini, L. M. (2022). O biodiesel na matriz energética brasileira: da sua inserção aos dias atuais. Revista Principia - Divulgação Científica e Tecnológica Do IFPB. https://doi.org/10.18265/1517-0306a2021id6316
Nascimento, T. L., Maciel, M. A. M., Bertini, L. M., & Rios, M. A. de S. (2020). Avaliação do óleo e biodiesel de soja (glycine max) a partir de parâmetros físico-químicos. Brazilian Journal of Development, 6(3), 12685–12694. https://doi.org/10.34117/bjdv6n3-218
Oliveira, E. P., Lasmar, D. J., Chaar, J. da S., da Silva, E. L., Lima, E. de Q., de Oliveira, R. P., de Oliveira, E. P., & Polari, L. B. (2022). Impactos da regulamentação da qualidade do Biodiesel para os agentes regulados na Região Norte / Impacts of Biodiesel Quality Regulation for Regulated Agents in the North Region. Brazilian Journal of Development, 7(12), 121730–121743. https://doi.org/10.34117/bjdv7n12-777
Queiroz, I. R., Costa, A. S. V. da., Almeida, I. C., Barros, G. F., Alves, W. M., Souza, M. C. de, Franco, M. L., Pompermayer, R. de S., Souza, A. O., & Ferreira, A. C. (2021). O biocombustível no Brasil: potencialidades da cultura do Crambe abyssinica para produção de biodiesel. Research, Society and Development, 10(5), e11510514618. https://doi.org/10.33448/rsd-v10i5.14618
Resolução ANP Nº 45 DE 25/08/2014 - Dispõe sobre a especificação do biodiesel contida no Regulamento Técnico ANP nº 3 de 2014 e as obrigações quanto ao controle da qualidade a serem atendidas pelos diversos agentes econômicos que comercializam o produto em todo o território nacional. ANP – Agência Nacional de Petróleo, Gás Natural e Biocombustíveis.
Rodrigues, A. C. C. (2021). Policy, regulation, development and future of biodiesel industry in Brazil. Cleaner Engineering and Technology, 4. https://doi.org/10.1016/j.clet.2021.100197
Silva, H. R. G., & Quitella, C. M. (2021). Estudo Prospectivo das Tecnologias Utilizadas para Redução das Emissões de Poluentes Causadas pelos Veículos a Diesel. Cadernos De Prospecção, 14, 1186–1200.
Steinke, G. Síntese Enzimática De Ésteres Metílicos A Partir De Óleo De Soja Bruto. Dissertação (Mestrado) – Universidade Federal da Fronteira Sul, Programa de Pós-Graduação em Ciência e Tecnologia de Alimentos - PPGCTAL, Laranjeiras do Sul, PR, 2018
Yang, Z., Ji, P., Li, Q., Jiang, Y., Zheng, C., Wang, Y., Gao, X., & Lin, R. (2019). Comprehensive understanding of SO3 effects on synergies among air pollution control devices in ultra-low emission power plants burning high-sulfur coal. Journal of Cleaner Production, 239. https://doi.org/10.1016/j.jclepro.2019.118096
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Copyright (c) 2022 Tassio Lessa do Nascimento; Maria Aparecida Medeiros Maciel; Maria Alexsandra Sousa Rios; Luciana Medeiros Bertini; Jonatas Martins Negueiro
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