Influencia del recubrimiento híbrido en la resistencia a la corrosión del titanio
DOI:
https://doi.org/10.33448/rsd-v11i11.33945Palabras clave:
Titanio; Anodizado; Precursores de alcóxido de silano.Resumen
Los biomateriales, luego de implantados, quedan en contacto con el fluido corporal, lo que contribuye a la corrosión de los materiales, comprometiendo su integridad en algunos tipos de biomateriales. Este trabajo tiene como objetivo estudiar la resistencia a la corrosión del titanio cuando se somete a fluido corporal simulado (SBF). Las muestras de titanio cp de grado 2 se anodizaron con 1 M H3PO4 y 1 M H3PO4 + 0,15 % HF p/v electrolito a 10 V durante 30 minutos. Los recubrimientos híbridos están compuestos por precursores de alcóxido de metacriloxipropiltrimetoxisilano (MPTS) y tetraetoxisilano (TEOS). Las muestras no anodizadas y anodizadas se recubrieron con el recubrimiento híbrido. El revestimiento se analizó usando espectroscopía infrarroja por transformada de Fourier (FTIR) y análisis de termogravimetría (TGA). Las muestras fueron analizadas con Microscopía Electrónica de Barrido (SEM), ángulo de contacto, polarización potenciodinámica, Potencial de Circuito Abierto (OCP) y Espectroscopía de Impedancia Electroquímica (EIE). Los resultados mostraron que la deposición del recubrimiento híbrido sobre las muestras anodizadas no fue efectiva como se esperaba, ya que la película depositada presentó irregularidades, indicando un mejor comportamiento corrosivo de las muestras únicamente anodizadas.
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