Efeito da modificação de um xerogel de sílica por dodecilsulfato de sódio para a adsorção do corante violeta cristal em meio aquoso
DOI:
https://doi.org/10.33448/rsd-v10i17.24470Palavras-chave:
Violeta cristal; Corante; Adsorção; Xerogéis de sílica.Resumo
O descarte incorreto de corantes tem sido uma das causas para a poluição de águas. Ações para reduzir estes impactos têm sido feitas, e uma alternativa é a adsorção de corantes em materiais à base de sílica como os xerogéis. Poucos relatos na literatura, entretanto, mostram a modificação de xerogéis à base de sílica usando tensoativos para adsorção de corantes. Neste trabalho, nós preparamos xerogéis à base de sílica (SiO2) para explorar a influência da modificação da superfície com dodecilsulfato de sódio (SDS) na adsorção de um corante, violeta cristal (VC), em água usando espectroscopia na região do ultra-violeta visível. As propriedades texturais dos xerogéis, SiO2 não modificado (SiO2-NM) e SiO2 modificado com SDS (SiO2-SDS) mostraram que as amostras são mesoporosas. As cargas superficiais para SiO2-NM e SiO2-SDS foram negativas nas condições experimentais usadas como mostrado pelos dados de pH no ponto de carga zero pH (PCZ). A capacidade de adsorção de SiO2-SDS para VC foi superior àquela para SiO2-NM, com maior constante de velocidade para SiO2-SDS. Este comportamento foi atribuído às micelas de SDS formadas nos poros da sílica seca, sugerindo interações eletrostáticas entre as cabeças polares aniônicas das micelas e o VC catiônico. As cinéticas de adsorção foram melhores ajustadas pelo modelo de pseudo segunda-ordem. Os dados de equilíbrio foram melhores descritos pelo modelo de isoterma de Langmuir. Os valores de qm de VC para SiO2-SDS foram de 25,8 mg g−1 e 1,59 mg g−1 on SiO2-NM. Estes resultados são importantes para auxiliar no tratamento de efluentes industriais.
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