Effect of the modification of a silica xerogel by sodium dodecyl sulfate for the adsorption of crystal violet dye in aqueous medium
DOI:
https://doi.org/10.33448/rsd-v10i17.24470Keywords:
Crystal violet; Dye; Adsorption; Silica xerogels.Abstract
The incorrect discharge of dyes has been one of the main causes of water pollution. Actions to reduce these impacts have been performed, and an alternative is through the adsorption of dyes on silica-based materials such as xerogels. Very few experiments, however, show the modification of silica-based xerogels using surfactants for dye adsorption applications. In this paper, we report the preparation of silica-based xerogels (SiO2) to explore the influence of the surface modification with sodium dodecyl sulfate (SDS) in the adsorption behavior of an organic dye, crystal violet (CV), from water using Ultra-Violet visible spectroscopy. The textural properties of the xerogels, SiO2 unmodified (SiO2-UN) and SiO2-SDS modified (SiO2-SDS) showed that the samples are mesoporous. The surface charges for SiO2-UN and SiO2-SDS were negative at experimental conditions as shown by pH point of zero charge (PZC) data. The adsorption capacity of SiO2-SDS for VC was superior to that of SiO2-UN and, in addition, SiO2-SDS had a higher rate constant. This behavior is probably ascribed to the presence of SDS micelles formed into the pores of wet silica xerogels, suggesting electrostatic interaction between anionic head groups from the micelles and cationic VC. The adsorption kinetics were best fitted by the pseudo-second order model. The equilibrium data were best described to the Langmuir isotherm model. The qm values of CV on SiO2-SDS reached 25,8 mg g−1 and 1,59 mg g−1 on SiO2-UN. These findings are important to help in the treatment of industrial wastewater.
References
Ahmad, R. (2009). Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP). Journal of Hazardous Materials, 171(1–3), 767–773. https://doi.org/10.1016/j.jhazmat.2009.06.060
Ain, Q. U., Zhang, H., Yaseen, M., Rasheed, U., Liu, K., Subhan, S., & Tong, Z. (2020). Facile fabrication of hydroxyapatite-magnetite-bentonite composite for efficient adsorption of Pb(II), Cd(II), and crystal violet from aqueous solution. Journal of Cleaner Production, 247(Ii), 119088. https://doi.org/10.1016/j.jclepro.2019.119088
Akpotu, S. O., & Moodley, B. (2018). Effect of synthesis conditions on the morphology of mesoporous silica from elephant grass and its application in the adsorption of cationic and anionic dyes. Journal of Environmental Chemical Engineering, 6(4), 5341–5350. https://doi.org/10.1016/j.jece.2018.08.027
B.Colthup, N., H. Daly, L., & E. Wiberley, S. (1990). Introduction to Infrared and Raman Spectroscopy (Third Edit). Academic Press.
Banat, I. M., Nigam, P., Singh, D., & Marchant, R. (1996). Microbial decolorization of textile-dye-containing effluents: A review. Bioresource Technology, 58(3), 217–227. https://doi.org/10.1016/S0960-8524(96)00113-7
Barrett, E. P., Joyner, L. G., & Halenda, P. P. (1951). The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms. Journal of the American Chemical Society, 73(1), 373–380. https://doi.org/10.1021/ja01145a126
Brinker, C. J., & Scherer, G. W. (1990). Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (First). Academic Press.
Bruzzoniti, M. C., De Carlo, R. M., Rivoira, L., Del Bubba, M., Pavani, M., Riatti, M., & Onida, B. (2016). Adsorption of bentazone herbicide onto mesoporous silica: application to environmental water purification. Environmental Science and Pollution Research, 23(6), 5399–5409. https://doi.org/10.1007/s11356-015-5755-1
Cheruiyot, G. K., Wanyonyi, W. C., Kiplimo, J. J., & Maina, E. N. (2019). Adsorption of toxic crystal violet dye using coffee husks: Equilibrium, kinetics and thermodynamics study. Scientific African, 5, 1–11. https://doi.org/10.1016/j.sciaf.2019.e00116
Cloarec, J. P., Chevalier, C., Genest, J., Beauvais, J., Chamas, H., Chevolot, Y., Baron, T., & Souifi, A. (2016). PH driven addressing of silicon nanowires onto Si3N4/SiO2 micro-patterned surfaces. Nanotechnology, 27(29). https://doi.org/10.1088/0957-4484/27/29/295602
Dabagh, A., Bagui, A., Abali, M., Aziam, R., Chiban, M., Sinan, F., & Zerbet, M. (2020). Adsorption of Crystal Violet from aqueous solution onto eco-friendly native Carpobrotus edulis plant. Materials Today: Proceedings, 37, 3980–3986. https://doi.org/10.1016/j.matpr.2020.10.349
Da̧browski, A. (2001). Adsorption - From theory to practice. Advances in Colloid and Interface Science, 93(1–3), 135–224. https://doi.org/10.1016/S0001-8686(00)00082-8
Dallago, R. M., Smaniotto, A., & Oliveira, L. C. A. de. (2005). Resíduos sólidos de curtumes como adsorventes para a remoção de corantes em meio aquoso. Química Nova, 28(3), 433–437. https://doi.org/10.1590/s0100-40422005000300013
Dorigon, L., Ruiz de Almeida da Frota, J. P., Kreutz, J. C., Mello Giona, R., Pereira Moisés, M., & Bail, A. (2017). Synthesis and characterization of mesoporous silica-coated magnetite containing cetyltrimethylammonium bromide and evaluation on the adsorption of sodium dodecylbenzenesulfonate. Applied Surface Science, 420, 954–962. https://doi.org/10.1016/j.apsusc.2017.05.249
Du, C., Song, Y., Shi, S., Jiang, B., Yang, J., & Xiao, S. (2020). Preparation and characterization of a novel Fe3O4-graphene-biochar composite for crystal violet adsorption. Science of the Total Environment, 711, 134662. https://doi.org/10.1016/j.scitotenv.2019.134662
Dudás, Z., Len, A., Ianăși, C., & Paladini, G. (2020). Structural modifications caused by the increasing MTES amount in hybrid MTES/TEOS-based silica xerogels. Materials Characterization, 167(April), 33–36. https://doi.org/10.1016/j.matchar.2020.110519
El-Dossoki, F. I., Gomaa, E. A., & Hamza, O. K. (2019). Solvation thermodynamic parameters for sodium dodecyl sulfate (SDS) and sodium lauryl ether sulfate (SLES) surfactants in aqueous and alcoholic-aqueous solvents. SN Applied Sciences, 1(8), 1–17. https://doi.org/10.1007/s42452-019-0974-6
Fabryanty, R., Valencia, C., Soetaredjo, F. E., Putro, J. N., Santoso, S. P., Kurniawan, A., Ju, Y. H., & Ismadji, S. (2017). Removal of crystal violet dye by adsorption using bentonite – alginate composite. Journal of Environmental Chemical Engineering, 5(6), 5677–5687. https://doi.org/10.1016/j.jece.2017.10.057
Febrianto, J., Kosasih, A. N., Sunarso, J., Ju, Y. H., Indraswati, N., & Ismadji, S. (2009). Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. Journal of Hazardous Materials, 162(2–3), 616–645. https://doi.org/10.1016/j.jhazmat.2008.06.042
Ferreira, B. C. S., Teodoro, F. S., Mageste, A. B., Gil, L. F., de Freitas, R. P., & Gurgel, L. V. A. (2015). Application of a new carboxylate-functionalized sugarcane bagasse for adsorptive removal of crystal violet from aqueous solution: Kinetic, equilibrium and thermodynamic studies. Industrial Crops and Products, 65(1), 521–534. https://doi.org/10.1016/j.indcrop.2014.10.020
Forgacs, E., Cserháti, T., & Oros, G. (2004). Removal of synthetic dyes from wastewaters: A review. Environment International, 30(7), 953–971. https://doi.org/10.1016/j.envint.2004.02.001
Ghosh, K., Bar, N., Biswas, A. B., & Das, S. K. (2021). Elimination of crystal violet from synthetic medium by adsorption using unmodified and acid-modified eucalyptus leaves with MPR and GA application. Sustainable Chemistry and Pharmacy, 19(December 2020), 100370. https://doi.org/10.1016/j.scp.2020.100370
Greluk, M., & Hubicki, Z. (2010). Kinetics, isotherm and thermodynamic studies of Reactive Black 5 removal by acid acrylic resins. Chemical Engineering Journal, 162(3), 919–926. https://doi.org/10.1016/j.cej.2010.06.043
Gupta, V. K., & Suhas. (2009). Application of low-cost adsorbents for dye removal - A review. Journal of Environmental Management, 90(8), 2313–2342. https://doi.org/10.1016/j.jenvman.2008.11.017
Hannachi, Y., & Hafidh, A. (2020). Preparation and characterization of novel bi-functionalized xerogel for removal of methylene blue and lead ions from aqueous solution in batch and fixed-bed modes: RSM optimization, kinetic and equilibrium studies. Journal of Saudi Chemical Society, 24(7), 505–519. https://doi.org/10.1016/j.jscs.2020.05.002
Ho, Y.S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465. https://doi.org/10.1021/acs.oprd.7b00090
Ho, Yuh Shan. (2004). Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics, 59(1), 171–177. https://doi.org/10.1023/B:SCIE.0000013305.99473.cf
Kaewprachum, W., Wongsakulphasatch, S., Kiatkittipong, W., Striolo, A., Cheng, C. K., & Assabumrungrat, S. (2020). SDS modified mesoporous silica MCM-41 for the adsorption of Cu2+, Cd2+, Zn2+ from aqueous systems. Journal of Environmental Chemical Engineering, 8(1). https://doi.org/10.1016/j.jece.2019.102920
Karim, A. H., Jalil, A. A., Triwahyono, S., Sidik, S. M., Kamarudin, N. H. N., Jusoh, R., Jusoh, N. W. C., & Hameed, B. H. (2012). Amino modified mesostructured silica nanoparticles for efficient adsorption of methylene blue. Journal of Colloid and Interface Science, 386(1), 307–314. https://doi.org/10.1016/j.jcis.2012.07.043
Katheresan, V., Kansedo, J., & Lau, S. Y. (2018). Efficiency of various recent wastewater dye removal methods: A review. Journal of Environmental Chemical Engineering, 6(4), 4676–4697. https://doi.org/10.1016/j.jece.2018.06.060
Kaur, S., Rani, S., & Mahajan, R. K. (2015). Adsorptive removal of dye crystal violet onto low-cost carbon produced from Eichhornia plant: kinetic, equilibrium, and thermodynamic studies. Desalination and Water Treatment, 53(2), 543–556. https://doi.org/10.1080/19443994.2013.841109
Khan, N. A., Bhadra, B. N., & Jhung, S. H. (2018). Heteropoly acid-loaded ionic liquid@metal-organic frameworks: Effective and reusable adsorbents for the desulfurization of a liquid model fuel. Chemical Engineering Journal, 334(November 2017), 2215–2221. https://doi.org/10.1016/j.cej.2017.11.159
Khurana, I., Saxena, A., Bharti, Khurana, J. M., & Rai, P. K. (2017). Removal of Dyes Using Graphene-Based Composites: a Review. Water, Air, and Soil Pollution, 228(5). https://doi.org/10.1007/s11270-017-3361-1
Langmuir, I. (1917). The Constitution and FUndamental Properties of SOlids and Liquids. II. Liquids. 1. Journal of the American Chemical Society, 39(9), 1848–1906. https://doi.org/10.1021/ja02254a006
Lee, Y. S., Jang, W., Koo, H. Y., & Choi, W. S. (2015). Facile synthesis of mesoporous SiO2 nanoparticles using the mobility differences of etchants. RSC Advances, 5(33), 26223–26230. https://doi.org/10.1039/c5ra01154j
Li, Y., Wang, S., Shen, Z., Li, X., Zhou, Q., Sun, Y., Wang, T., Liu, Y., & Gao, Q. (2020). Gradient Adsorption of Methylene Blue and Crystal Violet onto Compound Microporous Silica from Aqueous Medium. ACS Omega, 5(43), 28382–28392. https://doi.org/10.1021/acsomega.0c04437
Matsui, K., Nakazawa, T., & Morisaki, H. (1991). Micellar formation of sodium dodecyl sulfate in sol-gel glasses probed by pyrene fluorescence. Journal of Physical Chemistry, 95(2), 976–979. https://doi.org/10.1021/j100155a088
Mittal, A., Mittal, J., Malviya, A., Kaur, D., & Gupta, V. K. (2010). Adsorption of hazardous dye crystal violet from wastewater by waste materials. Journal of Colloid and Interface Science, 343(2), 463–473. https://doi.org/10.1016/j.jcis.2009.11.060
Nagappan, S., Jeon, Y., Park, S. S., & Ha, C. S. (2019). Hexadecyltrimethylammonium Bromide Surfactant-Supported Silica Material for the Effective Adsorption of Metanil Yellow Dye. ACS Omega, 4(5), 8548–8558. https://doi.org/10.1021/acsomega.9b00533
Nascimento, R. F. do, Lima, A. C. A. de, Vidal, C. B., Melo, D. de Q., & Raulino, G. S. C. (2014). Adsorção: Aspectos teóricos e aplicações ambientais. In Imprensa Universitária da Universidade Federal do Ceará (UFC).
Nordin, M. N., Asari, N., Mahaidin, A. A., Sha, K. M., & Aziz, N. M. A. N. A. (2016). Immobilization of Bromocresol Purple in Inorganic-Organic Sol-Gel Thin Film with Presence of Anionic and Non-ionic Surfactants. Procedia Chemistry, 19, 275–282. https://doi.org/10.1016/j.proche.2016.03.007
Olívio, P. H. de P., Buzato, G. V., & Souza, A. L. de. (2021). Influência da catálise ácida e básica na síntese de xerogéis de sílica para a adsorção de azul de metileno em meio aquoso Influence of acidic and basic catalysis on the synthesis of silica xerogels for the adsorption of methylene blue in aqueous medium In. Research, Society and Development, 10(15), e132101522524.
Parida, S. K., Dash, S., Patel, S., & Mishra, B. K. (2006). Adsorption of organic molecules on silica surface. Advances in Colloid and Interface Science, 121(1–3), 77–110. https://doi.org/10.1016/j.cis.2006.05.028
Price, P. M., Clark, J. H., & Macquarrie, D. J. (2008). Modi fi ed silicas for clean technology. Journal of the Chemical Society Dalton Transactions, 2, 101–110.
Rabie, A. M., Abd El-Salam, H. M., Betiha, M. A., El-Maghrabi, H. H., & Aman, D. (2019). Mercury removal from aqueous solution via functionalized mesoporous silica nanoparticles with the amine compound. Egyptian Journal of Petroleum, 28(3), 289–296. https://doi.org/10.1016/j.ejpe.2019.07.003
Rocha, L. C., De Souza, A. L., Rodrigues Filho, U. P., Campana Filho, S. P., Sette, L. D., & Porto, A. L. M. (2012). Immobilization of marine fungi on silica gel, silica xerogel and chitosan for biocatalytic reduction of ketones. Journal of Molecular Catalysis B: Enzymatic. https://doi.org/10.1016/j.molcatb.2012.05.025
Roik, N. V., Belyakova, L. A., Dziazko, M. O., & Oranska, O. I. (2020). Influence of azo dye additives on structural ordering of mesoporous silicas. Applied Nanoscience (Switzerland), 10(8), 2547–2556. https://doi.org/10.1007/s13204-019-01013-5
Saadi, R., Saadi, Z., Fazaeli, R., & Fard, N. E. (2015). Monolayer and multilayer adsorption isotherm models for sorption from aqueous media. Korean Journal of Chemical Engineering, 32(5), 787–799. https://doi.org/10.1007/s11814-015-0053-7
Sharma, M., Jain, P., Mishra, A., Mehta, A., Choudhury, D., Hazra, S., & Basu, S. (2017). Variation of surface area of silica monoliths by controlling ionic character/chain length of surfactants and polymers. Materials Letters, 194, 213–216. https://doi.org/10.1016/j.matlet.2017.02.074
Sulyman, M., Kucinska-Lipka, J., Sienkiewicz, M., & Gierak, A. (2021). Development, characterization and evaluation of composite adsorbent for the adsorption of crystal violet from aqueous solution: Isotherm, kinetics, and thermodynamic studies. Arabian Journal of Chemistry, 14(5), 103115. https://doi.org/10.1016/j.arabjc.2021.103115
Sulyman, M., Namiesnik, J., & Gierak, A. (2014). Utilization of new activated carbon derived from oak leaves for removal of crystal violet from aqueous solution. Polish Journal of Environmental Studies, 23(6), 2223–2232. https://doi.org/10.15244/pjoes/26764
Sun, L., Hu, S., Sun, H., Guo, H., Zhu, H., Liu, M., & Sun, H. (2015). Malachite green adsorption onto Fe3O4@SiO2-NH2: Isotherms, kinetic and process optimization. RSC Advances, 5(16), 11837–11844. https://doi.org/10.1039/c4ra13402h
Sun, P., Hui, C., Khan, R. A., Du, J., Zhang, Q., & Zhao, Y. H. (2015). Efficient removal of crystal violet using Fe3O4-coated biochar: The role of the Fe3O4 nanoparticles and modeling study their adsorption behavior. Scientific Reports, 5(March), 1–12. https://doi.org/10.1038/srep12638
Thommes, M., Kaneko, K., Neimark, A. V., Olivier, J. P., Rodriguez-Reinoso, F., Rouquerol, J., & Sing, K. S. W. (2015). Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 87(9–10), 1051–1069. https://doi.org/10.1515/pac-2014-1117
Uddin, M. K., Mashkoor, F., AlArifi, I. M., & Nasar, A. (2021). Simple one-step synthesis process of novel MoS2@bentonite magnetic nanocomposite for efficient adsorption of crystal violet from aqueous solution. Materials Research Bulletin, 139(November 2020), 111279. https://doi.org/10.1016/j.materresbull.2021.111279
Wang, J., & Guo, X. (2020). Adsorption isotherm models: Classification, physical meaning, application and solving method. Chemosphere, 258, 127279. https://doi.org/10.1016/j.chemosphere.2020.127279
Wu, Z., Ahn, I. S., Lee, C. H., Kim, J. H., Shul, Y. G., & Lee, K. (2004). Enhancing the organic dye adsorption on porous xerogels. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 240(1–3), 157–164. https://doi.org/10.1016/j.colsurfa.2004.04.045
Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science, 209, 172–184. https://doi.org/10.1016/j.cis.2014.04.002
Yaseen, D. A., & Scholz, M. (2019). Textile dye wastewater characteristics and constituents of synthetic effluents: a critical review. In International Journal of Environmental Science and Technology (Vol. 16, Issue 2). Springer Berlin Heidelberg. https://doi.org/10.1007/s13762-018-2130-z
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2021 Gabriel Vinicius Buzato; Pedro Henrique de Paulo Olívio; Adriano Lopes de Souza
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3) Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.
