Qualitative and quantitative transformations of physical-chemical parameters in aged cachaças
DOI:
https://doi.org/10.33448/rsd-v13i8.46629Keywords:
Drinks; Woods; Storage; Chemical markers.Abstract
The cachaça has been aged in barrels made from different types of wood in order to provide not only added value to the product but also unique organoleptic experiences for its consumers. This aging process has several singular nuances that make each product unique, which can be related to the species of wood, the cut used in making the barrels, the temperature and humidity of the aging location, the aging time, among other factors. Despite the many variables in the process, it is possible to determine the main transformation reactions that occur during this stage of production. The objective of this work was to perform a qualitative and quantitative evaluation of the compounds present in different samples of aged cachaças to better understand the transformations that occur during the aging period. The cachaças under study showed differences in chemical composition, a fact that was expected since the aging process tends to add compounds that modify the organoleptic characteristics of the beverages. It is worth noting that all samples comply with current legislation regarding the parameters analyzed. The beverages showed distinct values in the phenolic compounds analyzed, both in terms of concentration and identification. The cachaça aged in oak presented syringaldehyde (1.66 mg L-1) as the major compound, amburana showed coumarin (4.52 mg L-1), jequitibá exhibited vanillin (0.12 mg L-1), and the oak/chestnut blend had gallic acid (1.24 mg L-1) and syringaldehyde (2.08 mg L-1). Thus, it can be inferred that these major compounds found are potential chemical markers for the woods studied.
References
Anjos, J. P., Cardoso, M. G. Saczk, A. A., Zacaroni, L. M. & Santiago, W. D. (2011b). Identificação do carbamato de etila durante o armazenamento da cachaça em tonel de carvalho (Quercus sp.) e recipiente de vidro. Química Nova, 34(5), 874-8. https://doi.org/10.1590/S0100-40422011000500025
Anjos, J. P., Cardoso, M.G., Saczk, A.A., Dórea, H.S., Santiago, W. D., Machado, A. M. R., Zacaroni, L. M. & Nelson, D. L. (2011a). Evolution of the concentration of Phenolic compounds in cachaça during in na oak (Quercus sp.) barrel. Journal of the Brazilian Chemical Society, 22(7), 1307-14. https://doi.org/10.1590/S0103-50532011000700016
Barbosa, R. B., Alvarenga, G. F., Ferreira, V. R. F., Santiago, W. D., Nelson, D. L. & Cardoso, M. G. (2023). Cachaça sold in polyethylene terephthalate packaging: Determination of the physical-chemical profile, polycyclic aromatic hydrocarbons and ethyl carbamate. Ciência e Agrotecnlogia, 47. https://doi.org/10.1590/1413-7054202347007522
Barbosa, R. B., Santiago, W. D., Alvarenga, G. F., Oliveira, R. E. S., Ferreira, V. R. F., Nelson, D. L. & Cardoso, M. G. (2022). Physical-Chemical Profile and Quantification of Phenolic Compounds and Polycyclic Aromatic Hydrocarbons in Cachaça Samples Aged in Oak (Quercus sp.) Barrels with Different Heat Treatments. Food and Bioprocess Technology, 15, 1977-87. https://doi.org/10.1007/s11947-022-02853-w
Bigão, V. L. C. P., Silva, J. J. M., Cassiano, M. H. A., Costa, B. R. B., Gomes, N. C., Marinho, P. A., Rodrigues, C. H. P., Aguilar, G. J., Bruni, A. T., Tapia-Blácido, D. R. & Martinis, B. S. (2024). Uncovering the Counterfeit: A study of whiskey authenticity through volatile organic compound fingerprinting, aroma and color sensory analysis. Food Chemistry, 447, 2024. https://doi.org/10.1016/j.foodchem.2024.139023
Bortoletto, A. M., Silvello, G. C. & Alcarde, A. R. (2021). Aromatic profiling of flavour active compounds in sugarcane Spirits aged in tropical wooden barrels. Brazilian Journal of Food Technology, 24. https://doi.org/10.1590/1981-6723.07119
Brasil. Ministério da Agricultura e Pecuária. (2005). Instrução Normativa nº 24, de 08 de setembro de 2005. Aprova o Manual Operacional de Bebidas e Vinagres.
Brasil. Ministério da Agricultura e Pecuária. (2022). Portaria MAPA nº 539, de 26 de dezembro de 2022. Estabelece os Padrões de Identidade e Qualidade da aguardente de cana e cachaça. Diário Oficial da União, 27 de dezembro de 2022, Seção 1, p. 13.
Caetano, D., Lima, C. M. G., Sanson, A. L., Silva, D. F., Hassemer, G. S., Verruck, S., Gregório, S. R., Silva, G. A., Afonso, R. J. C. F., Coutrim, M. X., Batiha, G. E. & Simal-Gandara, J. (2002). Chemical fingerprint of non-aged artisanal sugarcane spirits using Kohonen artificial neural network. Food Analytical Methods, 25(4), 890-907. https://doi.org/10.1007/s12161-021-02160-8
Cardoso, M. G. (2020). Produção de aguardente de cana (4a ed.). Lavras: Editora UFLA.
Dias, S. M. B. C., Maia, A. B. R. A., & Nelson, D. L. (1998). Efeito de diferentes madeiras sobre a composição da aguardente de cana envelhecida. Ciência e Tecnologia de Alimentos, 18(3), 331-4. https://doi.org/10.1590/S0101-20611998000300014
Duarte, F. C., Cardoso, M. G., Santiago, W. D., Machado, A. M. R. & Nelson, D. L. (2017). Brazilian organic sugarcane Spirits: Physicochemical and chromatographic profile. Revista Ciência Agronômica, 48(2), 288-95. https://doi.org/10.5935/1806-6690.20170033
Ferreira, D. F. (2011). SISVAR: A computer statistical analysis system. Ciência e Agrotecnologia, 35(6), 1039-42. https://doi.org/10.1590/S1413-70542011000600001
Machado, A. M. R., Cardoso, M. G., Saczk, A. A., Anjos, J. P., Zacaroni, L. M., Dórea, H. S. & Nelson, D. L. (2013). Determination of ethyl carbamate in cachaça produced from copper stills by HPLC. Food Chemistry, 138, 1233-38. https://doi.org/10.1016/j.foodchem.2012.11.048
Nascimento, R. F., Marques, J. C., Lima Neto, B. S., Keukeleire, D. D. & Franco, D. W. (1997). Qualitative and quantitative high-performance liquid chromatographic analysis of aldehydes in Brazilian sugar cane spirits and other distilled alcoholic beverages. Journal of Chromatography A, 782(1), 13-23. https://doi.org/10.1016/S0021-9673(97)00425-1
Nunes, C. A., Freitas, M. P., Pinheiro, A. C. M. & Bastos, S. C. (2012). Chemoface: a novel free user-friendly interface for chemometrics. Journal of the Brazilian Chemical Society, 23(11), 2003-10. https://doi.org/10.1590/S0103-50532012005000073
Roullier-Gall, C., Signoret, J., Coelho, C., Hemmler, D., Kajdan, M., Lucio, M., Schafer, B., Gougeon, R. D. & Schmitt-Kopplin, P. (2020). Influence of regionality and maturation time on the chemical fingerprint of whisky. Food Chemistry, 323. https://doi.org/10.1016/j.foodchem.2020.126748
Santiago, W. D., Cardoso, M. G., & Nelson, D. L. (2017a). Cachaça stored in casks newly constructed of oak (Quercus sp.), amburana (Amburana cearensis), jatobá (Hymenaea courbaril), balsam (Myroxylon peruiferum), and peroba (Paratecoma peroba): Alcohol content, phenol composition, colour intensity and dry extract. Journal of the Institute of Brewing, 123(2), 232-41. https://doi.org/10.1002/jib.414
Santiago, W. D., Cardoso, M. G., Lunguinho, A. S., Barbosa, R. B., Cravo, F. D., Gonçalves, G. S. & Nelson, D. L. (2017b). Determination of ethyl carbamate in cachaça stored in newly made oak, amburana, jatobá, balsa, and peroba vats and in glass containers. Journal of the Institute of Brewing, 123(4), 572-78. https://doi.org/10.1002/jib.463
Santiago, W. D., Cardoso, M. G., Santiago, J. A., Gomes, M. S., Rodrigues, L. M. A., Brandão, R. M., Cardoso, R. R., D’ávila, G. B., Silva, B. L. & Caetano, A. R. S. (2014a). Comparison and quantification of the development of phenolic compounds during the aging of cachaça in oak (Quercus sp.) and amburana (Amburana cearensis) barrels. American Journal of Plant Sciences, 5(21), 3140-50. 10.4236/ajps.2014.521330
Santiago, W. D., Cardoso, M. G., Santiago, J. A., Teixeira, M. L., Barbosa, R. B., Zacaroni, L. M., Sales, P. F. & Nelson, D. L. (2016). Physicochemical profile and determination of volatile compounds in cachaça stored in new oak (Quercus sp.), amburana (Amburana cearensis), jatobá (Hymenaea courbaril), balsam (Myroxylon peruiferum), and peroba (Paratecoma peroba) casks by SPME-GC-MS. Journal of the Institute of Brewing, 122(4), 624-34. https://doi.org/10.1002/jib.372
Santiago, W. D., Cardoso, M. G., Zacaroni, L. M., Anjos, J. P., Machado, A. M. R. & Mendonça, J. G. P. (2012). Perfil físico-químico e quantificação de compostos fenólicos e acroleína em aguardente de cana-de-açúcar armazenadas em tonéis de diferentes madeiras. Revista Científica, 40(2), 189-97. https://doi.org/10.15361/1984-5529.2012v40n2p189%20-%20197
Teodoro, J. A. R., Pereira, H. V., Sena, M. M., Piccin, E., Zacca, J. J. & Augusti, R. (2017). Paper spray mass spectrometry and chemometric tools for a fast and reliable identification of counterfeit blended scottish whiskies. Food Chemistry, 237, 1058–64. https://doi.org/10.1016/j.foodchem.2017.06.062
Zacaroni, L. M., Cardoso, M. G., Saczk, A. A., Santiago, W. D. & Anjos, J. P. (2011). Caracterização e quantificação de contaminantes em aguardentes de cana. Química Nova, 34(2), 320-4. https://doi.org/10.1590/S0100-40422011000200026
Zacaroni, L. M., Cardoso, M. G., Santiago, W. D., Gomes, M. S., Duarte, F. C. & Nelson, D. L. (2015). Effect of light on the concentration of ethyl carbamate in cachaça stored in glass bottles. Journal of the Institute of Brewing, 121(2), 238-43. https://doi.org/10.1002/jib.214
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Marcos Aurélio Araújo Santiago; Wilder Douglas Santiago; Antonia Isadora Fernandes; Maria Luísa Teixeira; Sara Cristina Santos Silva; Danúbia Aparecida Carvalho Selvati Rezende; Maria das Graças Cardoso
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
1) Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2) Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
3) Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.