Membranas de nanocompuestos poliméricos de óxido de zinc para el tratamiento de aguas residuales: Revisión de la literatura
DOI:
https://doi.org/10.33448/rsd-v10i8.17402Palabras clave:
Inversión de fase; Membranas híbridas; Nanocompuestos; Tratamiento de aguas residuales.Resumen
La necesidad de aplicar tecnologías más limpias para el tratamiento de los efluentes y el agua son la clave para minimizar los impactos causados al medio ambiente y la recuperación de los recursos hídricos. Entre estas tecnologías destaca la tecnología de membranas porque presenta ventajas como el ahorro energético, la facilidad de operación, la sustitución de procesos convencionales, la recuperación de productos de alto valor añadido, la flexibilidad en el diseño de sistemas y el desarrollo de procesos híbridos. Este trabajo pretende realizar una revisión del proceso de separación por membranas, método de obtención y estudios recientes que utilizan el óxido de zinc (ZnO) como carga inorgánica para obtener membranas nanocompuestas. Las membranas híbridas han ido ganando espacio en la comunidad científica porque presentan mejoras en las propiedades físicas, mecánicas y químicas. A partir de los estudios realizados por los investigadores, se ha encontrado que el ZnO ha sido incorporado como carga para obtener membranas de nanocompuestos poliméricos, ya que presenta mejoras en su hidrofilia, flujo de agua, reducción del ensuciamiento y características de resistencia al cloro de las membranas obtenidas, presentando así potencial para ser aplicadas en el tratamiento de aguas residuales.
Citas
Agboola, O., Sunday Isaac Fayomi, O., Sadiku, R., Popoola, P., Adeniyi Alaba, P., & Adegbola, A. T. (2020). Polymers blends for the improvement of nanofiltration membranes in wastewater treatment: A short review. Materials Today: Proceedings, 43, 3365–3368. https://doi.org/10.1016/j.matpr.2020.05.387
Altun, V., Remigy, J. C., & Vankelecom, I. F. J. (2017). UV-cured polysulfone-based membranes: Effect of co-solvent addition and evaporation process on membrane morphology and SRNF performance. Journal of Membrane Science, 524, 729–737. https://doi.org/10.1016/j.memsci.2016.11.060
Amini, M., Seifi, M., Akbari, A., & Hosseinifard, M. (2020). Polyamide-zinc oxide-based thin film nanocomposite membranes: Towards improved performance for forward osmosis. Polyhedron, 179, 114362. https://doi.org/10.1016/j.poly.2020.114362
Anadão, P. (2010). Ciência e Tecnologia de Membranas. Artliber Editora Ltda. ISBN: 8588098504
Bellincanta, T., Poletto, P., Thürmer, M. B., Duarte, J., Toscan, A. Zeni, M. (2011). Preparação e caracterização de membranas poliméricas a partir da blenda polisulfona/ poliuretano. Polímeros, v. 21, p. 229-232.https://doi.org/10.1590/S0104-14282011005000045
Brasil, Lei. Ministério do Meio Ambiente. Conselho Nacional de Meio Ambiente - Conama. (2011). Resolução nº 430, de 13 de maio de 2011. Dispõe sobre as condições e padrões de lançamento de efluentes e altera a Resolução nº 357. http://www.suape.pe.gov.br/images/publicacoes/CONAMA_n.430.2011.pdf
Chinyerenwa, A. C., Wang, H., Zhang, Q., Zhuang, Y., Munna, K. H., Ying, C., Yang, H., & Xu, W. (2018). Structure and thermal properties of porous polylactic acid membranes prepared via phase inversion induced by hot water droplets. Polymer, 141, 62–69. https://doi.org/10.1016/j.polymer.2018.03.011
da Silva Barbosa Ferreira, R., Oliveira, S. S. L., Salviano, A. F., Araújo, E. M., Leite, A. M. D., & de Lucena Lira, H. (2019). Polyethersulfone hollow fiber membranes developed for oily emulsion treatment. Materials Research, 22, 1–8. https://doi.org/10.1590/1980-5373-MR-2018-0854
de Medeiros, K. M., Araújo, E. M., Lira, H. de L., Lima, D. de F., & Lima, C. A. P. de. (2017). Membranas microporosas híbridas assimétricas: Influência da argila na morfologia das membranas. Revista Materia, 22(2). https://doi.org/10.1590/S1517-707620170002.0144
Dinari, M., & Haghighi, A. (2018). Ultrasound-assisted synthesis of nanocomposites based on aromatic polyamide and modified ZnO nanoparticle for removal of toxic Cr(VI) from water. Ultrasonics Sonochemistry, 41(July 2017), 75–84. https://doi.org/10.1016/j.ultsonch.2017.09.023
El-Arnaouty, M. B., Abdel Ghaffar, A. M., Eid, M., Aboulfotouh, M. E., Taher, N. H., & Soliman, E.-S. (2018). Nano-modification of polyamide thin film composite reverse osmosis membranes by radiation grafting. Journal of Radiation Research and Applied Sciences, 11(3), 204–216. https://doi.org/10.1016/j.jrras.2018.01.005
Esfahani, M. R., Aktij, S. A., Dabaghian, Z., Firouzjaei, M. D., Rahimpour, A., Eke, J., Escobar, I. C., Abolhassani, M., Greenlee, L. F., Esfahani, A. R., Sadmani, A., & Koutahzadeh, N. (2019). Nanocomposite membranes for water separation and purification: Fabrication, modification, and applications. Separation and Purification Technology, 213(September 2018), 465–499. https://doi.org/10.1016/j.seppur.2018.12.050
Fathollah, P., Mortazavi. Y., Jafari. S. H., Khodadadi. A. (2015) Combination of plasma functionalization and phase inversion process techniques for efficient dispersion of MWCNTs in polyamide 6: assessment through morphological, electrical, rheological and thermal properties. Polymer-Plastics Technology and Engineering, v. 54, p. 632-638. https://doi.org/10.1080/03602559.2014.974269
Field, R. W. & Lipnizki, F. Membrane Separation Processes An Overview. In: Field, R. W., Bekassy-Molnar, E., Lipnizki, F., & Vatai, G. (2017). Engineering Aspects of Membrane Separation and Application in Food Processing, Boca Raton: CRC Press, ISBN 9781420083637
Fonseca Couto, C., Lange, L. C., & Santos Amaral, M. C. (2018). A critical review on membrane separation processes applied to remove pharmaceutically active compounds from water and wastewater. Journal of Water Process Engineering (Vol. 26, p. 156–175). Elsevier Ltd. https://doi.org/10.1016/j.jwpe.2018.10.010
Gebreslase, G. A. (2018). Review on Membranes for the Filtration of Aqueous Based Solution: Oil in Water Emulsion. Journal of Membrane Science & Technology, 08(02). https://doi.org/10.4172/2155-9589.1000188
Ghanbari Shohany, B., & Khorsand Zak, A. (2020). Doped ZnO nanostructures with selected elements - Structural, morphology and optical properties: A review. In Ceramics International (Vol. 46, Número 5, p. 5507–5520). Elsevier Ltd. https://doi.org/10.1016/j.ceramint.2019.11.051
Goh, P. S., & Ismail, A. F. (2018). A review on inorganic membranes for desalination and wastewater treatment. In Desalination (Vol. 434, p. 60–80). Elsevier B.V. https://doi.org/10.1016/j.desal.2017.07.023
Gohil, J. M., & Ray, P. (2017). A review on semi-aromatic polyamide TFC membranes prepared by interfacial polymerization: Potential for water treatment and desalination. In Separation and Purification Technology (Vol. 181, p. 159–182). Elsevier B.V. https://doi.org/10.1016/j.seppur.2017.03.020
Habert, A. C.; Borges C. P. & Nobrega, R. (2006) Processos de Separação por Membranas. Rio de Janeiro: E-papers. ISBN: 85-7650-085-X
Hairom, N. H. H., Mohammad, A. W., & Kadhum, A. A. H. (2014). Effect of various zinc oxide nanoparticles in membrane photocatalytic reactor for Congo red dye treatment. Separation and Purification Technology, 137, 74–81. https://doi.org/10.1016/j.seppur.2014.09.027
He, X., Chen, C., Jiang, Z., & Su, Y. (2011). Computer simulation of formation of polymeric ultrafiltration membrane via immersion precipitation. Journal of Membrane Science, 371(1–2), 108–116. https://doi.org/10.1016/j.memsci.2011.01.016
Hendricks. D. (2011). Fundamentals of Water Treatment Unit Processes: Physical, Chemical, and Biological. Boca Raton: IWA Publishing. ISBN: 13: 978-1-4200-6192-5
Isawi, H. (2018). Development of thin-film composite membranes via radical grafting with methacrylic acid/ ZnO doped TiO2 nanocomposites. Reactive and Functional Polymers, 131(September), 400–413. https://doi.org/10.1016/j.reactfunctpolym.2018.08.018
Iulianelli, A., & Drioli, E. (2020). Membrane engineering: Latest advancements in gas separation and pre-treatment processes, petrochemical industry and refinery, and future perspectives in emerging applications. In Fuel Processing Technology (Vol. 206, p. 106464). Elsevier B.V. https://doi.org/10.1016/j.fuproc.2020.106464
Kahouli, M., Barhoumi, A., Bouzid, A., Al-Hajry, A.,Guermazi, S. (2015). Structural and optical properties of ZnO nanoparticles prepared by direct precipitation method. In Superlattices and Microstructures (Vol. 85, p. 7–23). Academic Press. https://doi.org/10.1016/j.spmi.2015.05.007
Kausar. A .(2017) Phase inversion technique-based polyamide films and their applications: a comprehensive review. Polymer-Plastics Technology and Engineering, v. 56, p. 1421-1437. https://doi.org/10.1080/03602559.2016.1276593
Kazemi, F., Jafarzadeh, Y., Masoumi, S., & Rostamizadeh, M. (2021). Oil-in-water emulsion separation by PVC membranes embedded with GO-ZnO nanoparticles. Journal of Environmental Chemical Engineering, 9(1), 104992. https://doi.org/10.1016/j.jece.2020.104992
Khulbe, C. K., Feng, C.Y., Matsuura, T.( 2008) Synthetic polymeric membranes: characterization by atomic force microscopy. Berlin: Springer. ISBN: 978-3-540-73994-4
Leo, C. P., Cathie Lee, W. P., Ahmad, A. L., & Mohammad, A. W. (2012). Polysulfone membranes blended with ZnO nanoparticles for reducing fouling by oleic acid. Separation and Purification Technology, 89, 51–56. https://doi.org/10.1016/j.seppur.2012.01.002
Marana, N. L.; Sambrano, J. R.; Souza, A. R. (2010). Propriedades eletrônicas, estruturais e constantes elásticas do ZnO. Química Nova, v. 33, p. 810-815. https://doi.org/10.1590/S0100-40422010000400009
Matsuyama, H., Takida, Y., Maki, T., & Teramoto, M. (2002). Preparation of porous membrane by combined use of thermally induced phase separation and immersion precipitation. Polymer, 43(19), 5243–5248. https://doi.org/10.1016/S0032-3861(02)00409-3
Mayrinck, C.; Raphael, E.; Ferrari, J. L.; Schiavon, M. A. (2014). Síntese, propriedades e aplicações de óxido de zinco nanoestruturado. Revista Virtual de Química. v. 6, p. 1185-1204. DOI:10.5935/1984-6835.20140078
Mirzaei, H., & Darroudi, M. (2017). Zinc oxide nanoparticles: Biological synthesis and biomedical applications. In Ceramics International (Vol. 43, Número 1, p. 907–914). Elsevier Ltd. https://doi.org/10.1016/j.ceramint.2016.10.051
Mishra, Y. K., & Adelung, R. (2018). ZnO tetrapod materials for functional applications. In Materials Today (Vol. 21, Número 6, p. 631–651). Elsevier B.V. https://doi.org/10.1016/j.mattod.2017.11.003
Mulder, M. (1996) Basic Principles of Membrane Technology. Springer Netherlands. Second Edition. Kluwer Academic Publishers. IBSN:079234247X
Nasrollahi, N., Vatanpour, V., Aber, S., & Mahmoodi, N. M. (2018). Preparation and characterization of a novel polyethersulfone (PES) ultrafiltration membrane modified with a CuO/ZnO nanocomposite to improve permeability and antifouling properties. Separation and Purification Technology, 192(June 2017), 369–382. https://doi.org/10.1016/j.seppur.2017.10.034
Nath, K. (2017). Membrane Separation Processes. Second Edition, Delhi: PHI Learning. ISBN: 978-81-2035291-9
Naz, M. Y., Ahmad, S., Shukrullah, S., Altaf, N. U. H., & Ghaffar, A. (2020). Effect of microwave plasma treatment on membrane structure of polysulfone fabricated using phase inversion method. Materials Today: Proceedings. https://doi.org/10.1016/j.matpr.2020.04.522
Obreja, P., Cristea, D., Dinescu, A., & Romaniţan, C. (2019). Influence of surface substrates on the properties of ZnO nanowires synthesized by hydrothermal method. In Applied Surface Science (Vol. 463, p. 1117–1123). Elsevier B.V. https://doi.org/10.1016/j.apsusc.2018.08.191
Ozgur, U., Alivov, Y. I., Liu, C., Teke, A., Reshchicov, M. A., Dogan, S., Avrutin, V., Cho, S. J., Morkoç, H. (2005). A Comprehensive review of ZnO materials and devices. Journal of Applied Physics, v. 98, p. 1-104. https://doi.org/10.1063/1.1992666
Pabby, A. K., Rizvi, S. S. H. & Sastre, A. M. (2015). Handbook of Membrane Separations, Boca Raton: CRC Press. IBSN: 13: 978-1-4665-5558-7
Pal, N., Agarwal, M., Maheshwari, K., & Solanki, Y. S. (2020). A review on types, fabrication and support material of hydrogen separation membrane. Materials Today: Proceedings, 28, 1386–1391. https://doi.org/10.1016/j.matpr.2020.04.806
Pan, Z., Song, C., Li, L., Wang, H., Pan, Y., Wang, C., Li, J., Wang, T., & Feng, X. (2019). Membrane technology coupled with electrochemical advanced oxidation processes for organic wastewater treatment: Recent advances and future prospects. Chemical Engineering Journal, 376, 120909. https://doi.org/10.1016/j.cej.2019.01.188
Park, H. G., & Khang, D. Y. (2016). Asymmetric porous membranes from binary polymer solution by physical gelation induced phase separation. Polymer, 87, 323–329. https://doi.org/10.1016/j.polymer.2016.02.016
Ponnamma, D., Cabibihan, J. J., Rajan, M., Pethaiah, S. S., Deshmukh, K., Gogoi, J. P., Pasha, S. K. K., Ahamed, M. B., Krishnegowda, J., Chandrashekar, B. N., Polu, A. R., & Cheng, C. (2019). Synthesis, optimization and applications of ZnO/polymer nanocomposites. Materials Science and Engineering C, 98(December 2018), 1210–1240. https://doi.org/10.1016/j.msec.2019.01.081
Rajakumaran, R., Boddu, V., Kumar, M., Shalaby, M. S., Abdallah, H., & Chetty, R. (2019a). Effect of ZnO morphology on GO-ZnO modified polyamide reverse osmosis membranes for desalination. Desalination, 467(June), 245–256. https://doi.org/10.1016/j.desal.2019.06.018
Rajakumaran, R., Boddu, V., Kumar, M., Shalaby, M. S., Abdallah, H., & Chetty, R. (2019b). Effect of ZnO morphology on GO-ZnO modified polyamide reverse osmosis membranes for desalination. Desalination, 467, 245–256. https://doi.org/10.1016/j.desal.2019.06.018
Rajakumaran, R., Kumar, M., & Chetty, R. (2020). Morphological effect of ZnO nanostructures on desalination performance and antibacterial activity of thin-film nanocomposite (TFN) membrane. Desalination, 495(April), 114673. https://doi.org/10.1016/j.desal.2020.114673
Shaban, M., AbdAllah, H., Said, L., Hamdy, H. S., & Abdel Khalek, A. (2015). Titanium dioxide nanotubes embedded mixed matrix PES membranes characterization and membrane performance. Chemical Engineering Research and Design, 95, 307–316. https://doi.org/10.1016/j.cherd.2014.11.008
Sridhar, S., Moulik, S. Tackling Challenging Industrial Separation Problems through Membrane Technology. In: Sridhar, S., Moulik, S. Membrane Processes Pervaporation, Vapor Permeation and Membrane Distillation for Industrial Scale Separations. Hoboken: John Wiley & Sons, 2019. ISBN: 978-1-119-41835-1
Takht Ravanchi, M., Kaghazchi, T., & Kargari, A. (2009). Application of membrane separation processes in petrochemical industry: a review. Desalination, 235(1–3), 199–244. https://doi.org/10.1016/j.desal.2007.10.042
Tawalbeh, M., Al Mojjly, A., Al-Othman, A., & Hilal, N. (2018). Membrane separation as a pre-treatment process for oily saline water. In Desalination (Vol. 447, p. 182–202). Elsevier B.V. https://doi.org/10.1016/j.desal.2018.07.029
Torres-Trueba, A., Ruiz-Treviño, F. A., Luna-Bárcenas, G., & Ortiz-Estrada, C. H. (2008). Formation of integrally skinned asymmetric polysulfone gas separation membranes by supercritical CO2. Journal of Membrane Science, 320(1–2), 431–435. https://doi.org/10.1016/j.memsci.2008.04.024
Uragami, T. Science and Technology of Separation Membranes. Chichester: John Wiley & Sons Ltd, 2017. ISBN:9781118932544
Wu, Y., Gao, M., Chen, W., Lü, Z., Yu, S., Liu, M., & Gao, C. (2020). Efficient removal of anionic dye by constructing thin-film composite membrane with high perm-selectivity and improved anti-dye-deposition property. Desalination, 476, 114228. https://doi.org/10.1016/j.desal.2019.114228
Yong, W. F., & Zhang, H. (2021). Recent advances in polymer blend membranes for gas separation and pervaporation. In Progress in Materials Science (Vol. 116, p. 100713). Elsevier Ltd. https://doi.org/10.1016/j.pmatsci.2020.100713
Zang, Z., & Tang, X. (2015). Enhanced fluorescence imaging performance of hydrophobic colloidal ZnO nanoparticles by a facile method. Journal of Alloys and Compounds, 619, 98–101. https://doi.org/10.1016/j.jallcom.2014.09.072
Zhang, X., Wang, Y., Liu, Y., Xu, J., Han, Y., & Xu, X. (2014). Preparation, performances of PVDF/ZnO hybrid membranes and their applications in the removal of copper ions. Applied Surface Science, 316(1), 333–340. https://doi.org/10.1016/j.apsusc.2014.08.004
Zhu, L., Song, H., Wang, G., Zeng, Z., & Xue, Q. (2018). Symmetrical polysulfone/poly(acrylic acid) porous membranes with uniform wormlike morphology and pH responsibility: Preparation, characterization and application in water purification. Journal of Membrane Science, 549, 515–522. https://doi.org/10.1016/j.memsci.2017.12.052
Descargas
Publicado
Cómo citar
Número
Sección
Licencia
Derechos de autor 2021 José Everton Soares de Souza; Bruna Aline Araújo; Kênia Kelly Freitas Sarmento ; Larissa Dias Rebouças; Keila Machado de Medeiros; Carlos Antônio Pereira de Lima
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
Los autores que publican en esta revista concuerdan con los siguientes términos:
1) Los autores mantienen los derechos de autor y conceden a la revista el derecho de primera publicación, con el trabajo simultáneamente licenciado bajo la Licencia Creative Commons Attribution que permite el compartir el trabajo con reconocimiento de la autoría y publicación inicial en esta revista.
2) Los autores tienen autorización para asumir contratos adicionales por separado, para distribución no exclusiva de la versión del trabajo publicada en esta revista (por ejemplo, publicar en repositorio institucional o como capítulo de libro), con reconocimiento de autoría y publicación inicial en esta revista.
3) Los autores tienen permiso y son estimulados a publicar y distribuir su trabajo en línea (por ejemplo, en repositorios institucionales o en su página personal) a cualquier punto antes o durante el proceso editorial, ya que esto puede generar cambios productivos, así como aumentar el impacto y la cita del trabajo publicado.
