Adsorción de colorante amarillo ácido 17 sobre carbón activado preparado a partir de Euterpe oleracea: estudios cinéticos y termodinámicos
DOI:
https://doi.org/10.33448/rsd-v11i2.25556Palabras clave:
Adsorción; Carbón activado; Amarillo ácido 17.Resumen
La contaminación ambiental ha sido un punto de discusión en la comunidad internacional y objeto de estudio de diversos grupos de investigación, que se enfocan en el desarrollo de métodos de remediación. En el presente estudio, se utilizó el racimo de açaí (Euterpe oleracea) como precursor para la preparación de carbón activado de bajo costo, con el fin de eliminar el tinte amarillo ácido 17 (AY 17) en solución acuosa. La síntesis se llevó a cabo a temperaturas de 500, 600 y 700°C, durante 2,0 h en una mufla. El mecanismo cinético y termodinámico del proceso de adsorción del tinte AY 17, y los efectos del pH, el tiempo de contacto y la concentración inicial se investigaron utilizando el tipo de carbón activado con la mayor capacidad de remoción. El carbón activado a 700 °C tuvo la mayor capacidad de adsorción, con un 99,9% de remoción AY 17. La capacidad de adsorción del AY 17 fue ligeramente dependiente del pH, alcanzando un valor máximo a pH 2,0. Los datos cinéticos muestran que el tiempo de equilibrio fue de 200 min, y la capacidad de adsorción del carbón activado fue del 99,9% a 50 mg L-1 y del 67,0 % a 150 mg L-1 de adsorbato, sugiriendo una alta capacidad de adsorción del material, incluso en la presencia de una alta concentración de tinte. El proceso de adsorción de AY 17 se describe mediante el modelo cinético de pseudo-segundo orden, y las isotermas de adsorción experimentales se ajustan al modelo de Freundlich, lo que indica que la adsorción de AY 17 en carbón activado ocurre con la formación de multicapas. El presente estudio muestra que este material de bajo costo posee gran potencial para la remediación de efluentes textiles.
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