The influence of Ni and Co supported in the Brazilian diatomite for H2 production via methane dry reforming
DOI:
https://doi.org/10.33448/rsd-v10i11.19729Palavras-chave:
Diatominta; Níquel; Cobalto; Hidrogênio; Reforma a seco.Resumo
Brazilian diatomite was used as catalytic support for the dry reforming of methane. The active phases used were Ni and Co at different concentrations. The catalysts were calcined at 500 °C for 5 h and characterized by XRD, BET, TPR and SEM. The XRD results of the catalysts showed that there was formation of NiCo2O4 spinels for bimetallic catalysts, in addition to the expected NiO and Co3O4 phases. Catalytic tests were performed at 700 °C with a space velocity of 18 L⋅h-1⋅g-1, demonstrating a synergistic effect between the active phases (Ni and Co). The Ni8Co2/D catalyst showed the highest yield for H2, the best stability and the lowest rate of carbon formation between bimetallic catalysts. SEM results after the reaction indicated the presence of carbon filaments. According to the results, brazilian diatomite can be applied as a catalytic support in the dry reforming reaction of methane.
Referências
Costa, R. F., Mateus, P., & Barbosa, A. (2021). Secagem de placas cerâmicas híbridas argila/rejeito de diatomita : Um estudo experimental. Research, Society and Development, 10(8), e13710817174. https://doi.org/dx.doi.org/10.33448/rsd-v10i8.17174
E. J. Fernandes, R.C.M. Silva, H.Á. Oliveira, B.B. Toledo, M.B.T. Moura, F. B. P. (2014). Geração de hidrogênio pela decomposição catalítica do metano em catalisadores de Co/SiO2 promovidos por Ni e Fe. Engevista, 16(1), 41–49.
Estephane, J., Aouad, S., Hany, S., El Khoury, B., Gennequin, C., El Zakhem, H., El Nakat, J., Aboukaïs, A., & Abi Aad, E. (2015). CO2 reforming of methane over Ni-Co/ZSM5 catalysts. Aging and carbon deposition study. International Journal of Hydrogen Energy, 40(30), 9201–9208. https://doi.org/10.1016/j.ijhydene.2015.05.147
Fakeeha, A. H., Khan, W. U., Al-Fatesh, A. S., Abasaeed, A. E., & Naeem, M. A. (2015). Production of hydrogen and carbon nanofibers from methane over Ni-Co-Al catalysts. International Journal of Hydrogen Energy, 40(4), 1774–1781. https://doi.org/10.1016/j.ijhydene.2014.12.011
Gallego, G. S., Batiot-Dupeyrat, C., Barrault, J., Florez, E., & Mondragón, F. (2008). Dry reforming of methane over LaNi1-yByO3±δ (B = Mg, Co) perovskites used as catalyst precursor. Applied Catalysis A: General, 334(1–2), 251–258. https://doi.org/10.1016/j.apcata.2007.10.010
Gao, X., Tan, Z., Hidajat, K., & Kawi, S. (2017). Highly reactive Ni-Co/SiO2 bimetallic catalyst via complexation with oleylamine/oleic acid organic pair for dry reforming of methane. Catalysis Today, 281, 250–258. https://doi.org/10.1016/j.cattod.2016.07.013
García-Labiano, F., García-Díez, E., De Diego, L. F., Serrano, A., Abad, A., Gayán, P., Adánez, J., & Ruíz, J. A. C. (2015). Syngas/H2 production from bioethanol in a continuous chemical-looping reforming prototype. Fuel Processing Technology, 137, 24–30. https://doi.org/10.1016/j.fuproc.2015.03.022
Garcia, G., Cardenas, E., Cabrera, S., Hedlund, J., & Mouzon, J. (2016). Synthesis of zeolite y from diatomite as silica source. Microporous and Mesoporous Materials, 219, 29–37. https://doi.org/10.1016/j.micromeso.2015.07.015
Guo, S., & Shi, L. (2013). Synthesis of succinic anhydride from maleic anhydride on Ni/diatomite catalysts. Catalysis Today, 212, 137–141. https://doi.org/10.1016/j.cattod.2012.10.004
He, S., Zheng, X., Mo, L., Yu, W., Wang, H., & Luo, Y. (2014). Characterization and catalytic properties of Ni/SiO2 catalysts prepared with nickel citrate as precursor. Materials Research Bulletin, 49(1), 108–113. https://doi.org/10.1016/j.materresbull.2013.08.051
Huang, F., Wang, R., Yang, C., Driss, H., Chu, W., & Zhang, H. (2016). Catalytic performances of Ni/mesoporous SiO2 catalysts for dry reforming of methane to hydrogen. Journal of Energy Chemistry, 25(4), 709–719. https://doi.org/10.1016/j.jechem.2016.03.004
Jabbour, K., El Hassan, N., Davidson, A., Massiani, P., & Casale, S. (2015). Characterizations and performances of Ni/diatomite catalysts for dry reforming of methane. Chemical Engineering Journal, 264, 351–358. https://doi.org/10.1016/j.cej.2014.11.109
Li, B., Huang, H., Guo, Y., & Zhang, Y. (2015). Diatomite-immobilized BiOI hybrid photocatalyst: Facile deposition synthesis and enhanced photocatalytic activity. Applied Surface Science, 353, 1179–1185. https://doi.org/10.1016/j.apsusc.2015.07.049
Li, D., Chen, Y., Wang, H., Qiu, X., Alshameri, A., Ma, Y., Liu, Y., & Yan, C. (2014). An investigation into formation mechanism of amorphous hierarchical porous carbons by diatomite as template: Effect of furfuryl alcohol and glucose. Journal of the Taiwan Institute of Chemical Engineers, 45(5), 2742–2748. https://doi.org/10.1016/j.jtice.2014.05.010
Liu, H., Yao, L., Hadj Taief, H. B., Benzina, M., Da Costa, P., & Gálvez, M. E. (2018). Natural clay-based Ni-catalysts for dry reforming of methane at moderate temperatures. Catalysis Today, 306, 51–57. https://doi.org/10.1016/j.cattod.2016.12.017
Luisetto, I., Sarno, C., De Felicis, D., Basoli, F., Battocchio, C., Tuti, S., Licoccia, S., & Di Bartolomeo, E. (2017). Ni supported on γ-Al2O3 promoted by Ru for the dry reforming of methane in packed and monolithic reactors. Fuel Processing Technology, 158, 130–140. https://doi.org/10.1016/j.fuproc.2016.12.015
Medeiros, R. L. B. A., Macedo, H. P., Melo, V. R. M., Oliveira, Â. A. S., Barros, J. M. F., Melo, M. A. F., & Melo, D. M. A. (2016). Ni supported on Fe-doped MgAl2O4 for dry reforming of methane: Use of factorial design to optimize H2 yield. International Journal of Hydrogen Energy, 41(32), 14047–14057. https://doi.org/10.1016/j.ijhydene.2016.06.246
Mette, K., Kühl, S., Tarasov, A., Düdder, H., Kähler, K., Muhler, M., Schlögl, R., & Behrens, M. (2015). Redox dynamics of Ni catalysts in CO2 reforming of methane. Catalysis Today, 242(Part A), 101–110. https://doi.org/10.1016/j.cattod.2014.06.011
Nascimento, C. R., Sobrinho, E. M. O., Assis, R. B., Fagundes, R. F., Bieseki, L., & Pergher, S. B. C. (2014). Síntese da zeólita A utilizando diatomita como fonte de sílicio e alumínio. Ceramica, 60(353), 63–68. https://doi.org/10.1590/S0366-69132014000100009
Németh, M., Schay, Z., Srankó, D., Károlyi, J., Sáfrán, G., Sajó, I., & Horváth, A. (2015). Impregnated Ni/ZrO2 and Pt/ZrO2 catalysts in dry reforming of methane: Activity tests in excess methane and mechanistic studies with labeled 13CO2. Applied Catalysis A: General, 504, 608–620. https://doi.org/10.1016/j.apcata.2015.04.006
Pirsaraei, A., Reza, S., Hasan, A. M., Ahmad, J. J., Zohreh, F., & Jafar, T. (2015). The Effect of Acid and Thermal Treatment on a Natural Diatomite. Chemistry Journal, 1(4), 144–150. http://www.aiscience.org/journal/cjhttp://creativecommons.org/licenses/by-nc/4.0/
Romário, C. P. C. et al. (2021). Development of CuO-based oxygen carriers supported on diatomite and kaolin for chemical looping combustion. Research, Society and Development, 10(4), e15110412831. https://doi.org/dx.doi.org/10.33448/rsd-v10i4.12831
Taherian, Z., Yousefpour, M., Tajally, M., & Khoshandam, B. (2017). Promotional effect of samarium on the activity and stability of Ni-SBA-15 catalysts in dry reforming of methane. Microporous and Mesoporous Materials, 251, 9–18. https://doi.org/10.1016/j.micromeso.2017.05.027
Tanniratt, P., Wasanapiarnpong, T., Mongkolkachit, C., & Sujaridworakun, P. (2016). Utilization of industrial wastes for preparation of high performance ZnO/diatomite hybrid photocatalyst. Ceramics International, 42(15), 17605–17609. https://doi.org/10.1016/j.ceramint.2016.08.074
Thommes, M., Kaneko, K., Neimark, A. V., Olivier, J. P., Rodriguez-Reinoso, F., Rouquerol, J., & Sing, K. S. W. (2015). Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 87(9–10), 1051–1069. https://doi.org/10.1515/pac-2014-1117
Wang, M., Zhang, Q., Zhang, T., Wang, Y., Wang, J., Long, K., Song, Z., Liu, X., & Ning, P. (2017). Facile one-pot synthesis of highly dispersed Ni nanoparticles embedded in HMS for dry reforming of methane. Chemical Engineering Journal, 313, 1370–1381. https://doi.org/10.1016/j.cej.2016.11.055
Wang, X., Wen, W., Mi, J., Li, X., & Wang, R. (2015). The ordered mesoporous transition metal oxides for selective catalytic reduction of NOx at low temperature. Applied Catalysis B: Environmental, 176–177, 454–463. https://doi.org/10.1016/j.apcatb.2015.04.038
Wang, Y., Zhang, D., & Cai, J. (2016). Fabrication and characterization of flaky core-shell particles by magnetron sputtering silver onto diatomite. Applied Surface Science, 363, 122–127. https://doi.org/10.1016/j.apsusc.2015.11.148
Xia, Y., Jiang, X., Zhang, J., Lin, M., Tang, X., Zhang, J., & Liu, H. (2017). Synthesis and characterization of antimicrobial nanosilver/diatomite nanocomposites and its water treatment application. Applied Surface Science, 396, 1760–1764. https://doi.org/10.1016/j.apsusc.2016.11.222
Yasyerli, S., Filizgok, S., Arbag, H., Yasyerli, N., & Dogu, G. (2011). Ru incorporated Ni-MCM-41 mesoporous catalysts for dry reforming of methane: Effects of Mg addition, feed composition and temperature. International Journal of Hydrogen Energy, 36(8), 4863–4874. https://doi.org/10.1016/j.ijhydene.2011.01.120
Yu, J., Zhang, Z., Dallmann, F., Zhang, J., Miao, D., Xu, H., Goldbach, A., & Dittmeyer, R. (2016). Facile synthesis of highly active Rh/Al2O3 steam reforming catalysts with preformed support by flame spray pyrolysis. Applied Catalysis B: Environmental, 198, 171–179. https://doi.org/10.1016/j.apcatb.2016.05.050
Zhang, R. J., Xia, G. F., Li, M. F., Wu, Y., Nie, H., & Li, D. D. (2015). Effect of support on catalytic performance of Ni-based catayst in methane dry reforming. Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 43(11), 1359–1365. https://doi.org/10.1016/S1872-5813(15)30040-2
Downloads
Publicado
Como Citar
Edição
Seção
Licença
Copyright (c) 2021 Gineide Conceição Anjos; Ângelo Anderson Silva de Oliveira; Dulce Maria de Araújo Melo; Rodolfo Luis Bezerra de Araújo Medeiros; Cássia Carvalho de Almeida; Elania Maria Fernandes Silva; Eledir Vitor Sobrinho
![Creative Commons License](http://i.creativecommons.org/l/by/4.0/88x31.png)
Este trabalho está licenciado sob uma licença Creative Commons Attribution 4.0 International License.
Autores que publicam nesta revista concordam com os seguintes termos:
1) Autores mantém os direitos autorais e concedem à revista o direito de primeira publicação, com o trabalho simultaneamente licenciado sob a Licença Creative Commons Attribution que permite o compartilhamento do trabalho com reconhecimento da autoria e publicação inicial nesta revista.
2) Autores têm autorização para assumir contratos adicionais separadamente, para distribuição não-exclusiva da versão do trabalho publicada nesta revista (ex.: publicar em repositório institucional ou como capítulo de livro), com reconhecimento de autoria e publicação inicial nesta revista.
3) Autores têm permissão e são estimulados a publicar e distribuir seu trabalho online (ex.: em repositórios institucionais ou na sua página pessoal) a qualquer ponto antes ou durante o processo editorial, já que isso pode gerar alterações produtivas, bem como aumentar o impacto e a citação do trabalho publicado.