Kinetic study of peanut seed oil extraction with supercritical CO2
DOI:
https://doi.org/10.33448/rsd-v11i4.27098Keywords:
Supercritical extraction; Supercritical fluid; CO2; Kinetic study; Peanut.Abstract
Due to the need to create new technologies for the production of biofuels, there are techniques to perform oil extraction from oilseeds, such as the supercritical extraction method using CO2, where the seed used to carry out the study (peanut) is subjected to CO2 at high pressures and temperatures, thus becoming a supercritical fluid and carrying out the process of extracting the oil from the seed to produce biodiesel more efficiently. There is another extraction technique in which organic solvents are used. Still, this method has some difficulties that end up causing damage to the environment as it is a process that consumes a significant amount of time and energy. Peanut is the world's fourth-most cultivated oilseed, with large plantations in the Americas, Africa, and Asia. Its planting is carried out to produce grains, oil, and bran. CO2 has interesting physicochemical properties since it is an inert, non-polar, non-flammable, odorless, tasteless gas and has critical parameters and low value. It has a critical pressure of 72.01 bar and a critical temperature of 31.1 °C. The present work presents data from a kinetic study of the supercritical extraction of peanut oil under pressure and temperature conditions of 200 bar, 280 bar, 40 °C, and 60 °C. This project uses an experimental matrix to help carry out the experiments. At the end of the experiments, we obtained a yield of 30% in the supercritical method (80 min) and a percentage yield of 26% by Soxhlet using ethanol as a solvent for 480 minutes.
References
Andersen, P. C., & Gorbet, D. W. (2002). Influence of Year and Planting Date on Fatty Acid Chemistry of High Oleic Acid and Normal Peanut Genotypes. Journal of Agricultural and Food Chemistry, 50(5), 1298–1305. https://doi.org/10.1021/jf0113171
Araújo, O. A. S., Silva, F. R., Ramos, L. P., Lenzi, M. K., Ndiaye, P. M., & Corazza, M. L. (2012). Phase behaviour measurements for the system (carbon dioxide+biodiesel+ethanol) at high pressures. The Journal of Chemical Thermodynamics, 47, 412–419. https://doi.org/10.1016/j.jct.2011.11.029
Arce, P. F., Vieira, N. F., & Igarashi, E. M. S. (2018). Thermodynamic Modeling and Simulation of Biodiesel Systems at Supercritical Conditions. Industrial & Engineering Chemistry Research, 57(2), 751–767. https://doi.org/10.1021/acs.iecr.7b04195
Arya, S. S., Salve, A. R., & Chauhan, S. (2016). Peanuts as functional food: a review. Journal of Food Science and Technology, 53(1), 31–41. https://doi.org/10.1007/s13197-015-2007-9
Fazelifar, P., Tabrizi, M. H., & Rafiee, A. (2021). The Arachis hypogaea Essential Oil Nanoemulsion as an Efficient Safe Apoptosis Inducer in Human Lung Cancer Cells (A549). Nutrition and Cancer, 73(6), 1059–1067. https://doi.org/10.1080/01635581.2020.1783330
Ferreira, F. M., Ramos, L. P., Ndiaye, P. M., & Corazza, M. L. (2011). Phase behavior of (CO2+methanol+lauric acid) system. The Journal of Chemical Thermodynamics, 43(7), 1074–1082. https://doi.org/10.1016/j.jct.2011.02.017
Fogang, H. P. D., Maggi, F., Tapondjou, L. A., Womeni, H. M., Papa, F., Quassinti, L., … Barboni, L. (2014). In vitro Biological Activities of Seed Essential Oils from the Cameroonian Spices Afrostyrax lepidophyllus Mildbr . and Scorodophloeus zenkeri Harms Rich in Sulfur-Containing Compounds. Chemistry & Biodiversity, 11(1), 161–169. https://doi.org/10.1002/cbdv.201300237
Garcia, V. A. D. S., Cabral, V. F., Zanoelo, É. F., da Silva, C., & Filho, L. C. (2012). Extraction of Mucuna seed oil using supercritical carbon dioxide to increase the concentration of l-Dopa in the defatted meal. The Journal of Supercritical Fluids, 69, 75–81. https://doi.org/10.1016/j.supflu.2012.05.007
Gonçalves, R. M., Lemos, C. O. T., Leal, I. C. R., Nakamura, C. V., Cortez, D. A. G., da Silva, E. A., … Cardozo-Filho, L. (2013). Comparing conventional and supercritical extraction of (-)-mammea A/BB and the antioxidant activity of Calophyllum brasiliense extracts. Molecules (Basel, Switzerland), 18(6), 6215–6229. https://doi.org/10.3390/molecules18066215
Lemos, C. O. T., Garcia, V. A. D. S., Gonçalves, R. M., Leal, I. C. R., Siqueira, V. L. D., Filho, L. C., & Cabral, V. F. (2012). Supercritical extraction of neolignans from Piper regnelli var. pallescens. The Journal of Supercritical Fluids, 71, 64–70. https://doi.org/10.1016/j.supflu.2012.07.003
Papa Matar Ndiaye. (2004). Equilíbrio de fases de óleos vegetais e de biodiesel em CO2, propano e n-butano. Universidade Federal do Rio de Janeiro.
Paraízo, A.; Junior, E.; Paraízo, J. (2005). Produção de Biodiesel. Universidade Federal de Santa Catarina - SC.
Pinto, L. F., da Silva, D. I. S., Rosa da Silva, F., Ramos, L. P., Ndiaye, P. M., & Corazza, M. L. (2012). Phase equilibrium data and thermodynamic modeling of the system (CO2+biodiesel+methanol) at high pressures. The Journal of Chemical Thermodynamics, 44(1), 57–65. https://doi.org/10.1016/j.jct.2011.07.019
Rogério Favareto. (n.d.). Extração de compostos bioativos utilizando CO2 supercrítico de espécies do cerrado. Instituto Federal de Educação, Ciência e Tecnologia Goiano – Campus Rio Verde.
Serres, J. D. S., Soares, D., Corazza, M. L., Krieger, N., & Mitchell, D. a. (2015). Liquid–liquid equilibrium data and thermodynamic modeling for systems related to the production of ethyl esters of fatty acids from soybean soapstock acid oil. Fuel, 147, 147–154. https://doi.org/10.1016/j.fuel.2015.01.059
Silva, D. I. S., Mafra, M. R., da Silva, F. R., Ndiaye, P. M., Ramos, L. P., Cardozo Filho, L., & Corazza, M. L. (2013). Liquid–liquid and vapor–liquid equilibrium data for biodiesel reaction–separation systems. Fuel, 108, 269–276. https://doi.org/10.1016/j.fuel.2013.02.059
Silva, M. O., Camacho, F. P., Ferreira-Pinto, L., Giufrida, W. M., Vieira, A. M. S., Visentaine, J. V., … Cardozo-Filho, L. (2016). Extraction and phase behaviour of Moringa oleifera seed oil using compressed propane. The Canadian Journal of Chemical Engineering, 94(11), 2195–2201. https://doi.org/10.1002/cjce.22614
Souza, A. T., Benazzi, T. L., Grings, M. B., Cabral, V., Silva, E. A., Cardozo-Filho, L., & Ceva Antunes, O. A. (2008). Supercritical extraction process and phase equilibrium of Candeia (Eremanthus erythropappus) oil using supercritical carbon dioxide. The Journal of Supercritical Fluids, 47(2), 182–187. https://doi.org/10.1016/j.supflu.2008.08.001
Stat-Ease, I. (2008). Design Expert Software Version 7.1.3. Minneapolis, USA.
StatSoft, I. (2008). Statistica: Data Analysis Software System Version 8.0. Tulsa, USA.
Toledo, I. E. P., Ferreira-Pinto, L., Voll, F. A. P., Cardozo-Filho, L., Meili, L., Coêlho, D. de G., … Soletti, J. I. (2019). Liquid–Liquid Equilibrium of the System {Peanut Biodiesel + Glycerol + Ethanol} at Atmospheric Pressure. Journal of Chemical & Engineering Data, 64(5), 2207–2212. https://doi.org/10.1021acs.jced.8b01185
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Copyright (c) 2022 Guilherme de Souza Lopes; Paulo Cardozo Carvalho de Araujo; Michael Jones da Silva; Leonardo Lataro Paim; Kleber Rocha de Oliveira; Osvaldo Valarini Junior; Rogerio Favareto; Marcela Prado Silva Parizi; Leandro Ferreira-Pinto
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