Celulosa (Mangifera indica) modificada por melamina-sílice aplicada en el tratamiento de efluentes con precipitación asistida químicamente
DOI:
https://doi.org/10.33448/rsd-v10i6.15331Palabras clave:
Mangifera indica; Celulosa; CEPT; Azul de metileno; Adsorción.Resumen
Este trabajo tuvo como objetivo desarrollar un composite a base de celulosa, melamina y sílice. La celulosa se obtuvo de los residuos de poda de Mangifera indica para el tratamiento primario asistido químicamente de efluentes de la industria textil. El compuesto se caracterizó por FT-IR, MEV, MET, TG-DTG y Zeta Potential. Se aplicó la planificación central del compuesto para optimizar la masa del compuesto y el tiempo de contacto para eliminar el azul de metileno. FT-IR mostró que el composite presentaba la banda de melamina a 815 cm-1. SEM y MET revelaron que en la superficie compuesta hay nitrógeno de melamina, silicio y sodio del catalizador. TG-DTG demostró que el material compuesto es térmicamente más estable que la celulosa, con un 65% de degradación. Debido al potencial zeta, los valores de pH superiores a 5 proporcionan una mayor estabilización y aumentan el carácter aniónico del material compuesto. Se eligió como la mejor condición para la aplicación de 60 mg de composite y 30 minutos de tiempo de contacto, con remoción del 88,6 ± 3,5% del azul de metileno. El estudio de pH reveló que por encima de 5, el compuesto es más eficiente. El proceso de adsorción del tinte por el material fue consistente con el modelo de Langmuir (R2 = 0.9921). Así, el compuesto de celulosa-melamina-sílice desarrollado fue eficaz para eliminar el colorante azul de metileno, presentándose como un material de bajo costo, biodegradable y eficiente, con potencial de aplicación en el tratamiento de efluentes de la industria textil.
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Agwuncha, S. C., Owonubi, S., Fapojuwo, D. P., Abdulkarim, A., Okonkwo, T. P., & Makhatha, E. M. (2020). Evaluation of mercerization treatment conditions on extracted cellulose from shea nut shell using FTIR and thermogravimetric analysis. Materials Today: Proceedings, xxxx. https://doi.org/10.1016/j.matpr.2020.05.473
AL-Hammadi, S. A., Al-Absi, A. A., Bin-Dahman, O. A., & Saleh, T. A. (2018). Poly(trimesoyl chloride-melamine) grafted on palygorskite for simultaneous ultra-trace removal of methylene blue and toxic metals. Journal of Environmental Management, 226(August), 358–364. https://doi.org/10.1016/j.jenvman.2018.08.025
Alencar, W. S., Acayanka, E., Lima, E. C., Royer, B., de Souza, F. E., Lameira, J., & Alves, C. N. (2012). Application of Mangifera indica (mango) seeds as a biosorbent for removal of Victazol Orange 3R dye from aqueous solution and study of the biosorption mechanism. Chemical Engineering Journal, 209, 577–588. https://doi.org/10.1016/j.cej.2012.08.053
Alila, S., Besbes, I., Vilar, M. R., Mutjé, P., & Boufi, S. (2013). Non-woody plants as raw materials for production of microfibrillated cellulose (MFC): A comparative study. Industrial Crops and Products, 41(1), 250–259. https://doi.org/10.1016/j.indcrop.2012.04.028
Ameen, F., Srinivasan, P., Selvankumar, T., Kamala-Kannan, S., Al Nadhari, S., Almansob, A., Dawoud, T., & Govarthanan, M. (2019). Phytosynthesis of silver nanoparticles using Mangifera indica flower extract as bioreductant and their broad-spectrum antibacterial activity. Bioorganic Chemistry, 88(April), 102970. https://doi.org/10.1016/j.bioorg.2019.102970
Banat, F., Al-Asheh, S., Al-Ahmad, R., & Bni-Khalid, F. (2007). Bench-scale and packed bed sorption of methylene blue using treated olive pomace and charcoal. Bioresource Technology, 98(16), 3017–3025. https://doi.org/10.1016/j.biortech.2006.10.023
Banerjee, S., Gautam, R. K., Jaiswal, A., Chattopadhyaya, M. C., & Sharma, Y. C. (2015). Rapid scavenging of methylene blue dye from a liquid phase by adsorption on alumina nanoparticles. RSC Advances, 5(19), 14425–14440. https://doi.org/10.1039/c4ra12235f
Başaran Kankılıç, G., & Metin, A. Ü. (2020). Phragmites australis as a new cellulose source: Extraction, characterization and adsorption of methylene blue. Journal of Molecular Liquids, 312. https://doi.org/10.1016/j.molliq.2020.113313
Beh, J. H., Lim, T. H., Lew, J. H., & Lai, J. C. (2020). Cellulose nanofibril-based aerogel derived from sago pith waste and its application on methylene blue removal. International Journal of Biological Macromolecules, 160, 836–845. https://doi.org/10.1016/j.ijbiomac.2020.05.227
Bogolitsyn, K. G., Zubov, I. N., Gusakova, M. A., Chukhchin, D. G., & Krasikova, A. A. (2015). Juniper wood structure under the microscope. Planta, 241(5), 1231–1239. https://doi.org/10.1007/s00425-015-2252-1
Bonetto, L. R., Crespo, J. S., Guégan, R., Esteves, V. I., & Giovanela, M. (2021). Removal of methylene blue from aqueous solutions using a solid residue of the apple juice industry: Full factorial design, equilibrium, thermodynamics and kinetics aspects. Journal of Molecular Structure, 1224, 129296. https://doi.org/10.1016/j.molstruc.2020.129296
Cai, H., Du, F., Li, L., Li, B., Li, J., & Shi, H. (2019). A practical approach based on FT-IR spectroscopy for identification of semi-synthetic and natural celluloses in microplastic investigation. Science of the Total Environment, 669, 692–701. https://doi.org/10.1016/j.scitotenv.2019.03.124
Chen, Q. J., Kang, M. C., Xie, Q. H., & Wang, J. H. (2020). Effect of melamine modified cellulose nanocrystals on the performance of oil-immersed transformer insulation paper. Cellulose, 27(13), 7621–7636. https://doi.org/10.1007/s10570-020-03305-4
Choi, J., Fuentes, C., Fransson, J., Wahlgren, M., & Nilsson, L. (2020). Separation and zeta-potential determination of proteins and their oligomers using electrical asymmetrical flow field-flow fractionation (EAF4). Journal of Chromatography A, 1633, 461625. https://doi.org/10.1016/j.chroma.2020.461625
Crothers, A. R., Li, C., & Radke, C. J. (2021). A grahame triple-layer model unifies mica monovalent ion exchange, zeta potential, and surface forces. Advances in Colloid and Interface Science, 288(65), 102335. https://doi.org/10.1016/j.cis.2020.102335
Deeksha, B., Sadanand, V., Hariram, N., & Rajulu, A. V. (2021). Preparation and properties of cellulose nanocomposite fabrics with in situ generated silver nanoparticles by bioreduction method. Journal of Bioresources and Bioproducts, 6(1), 75–81. https://doi.org/10.1016/j.jobab.2021.01.003
Dong, Y., Zhang, H., Zhong, G., Yao, G., & Lai, B. (2021). Cellulose / carbon Composites and their Applications in Water Treatment – a Review. Chemical Engineering Journal, 405(August 2020). https://doi.org/10.1016/j.cej.2020.126980
El-Bouraie, M. (2015). Removal of the Malachite Green (MG) Dye From Textile Industrial Wastewater Using the Polyurethane Foam Functionalized with Salicylate. Journal of Dispersion Science and Technology, 36(9), 1228–1236. https://doi.org/10.1080/01932691.2014.964802
El-kott, A., Syef, A. F. A., Alshehri, M. A., Al Dessouky, S. I., & Keshk, S. M. A. S. (2019). Suppression efficacy of lignosulfonate/mercerized cotton fiber composite against cancer cell’s activities. Advanced Composites Letters, 28, 1–9. https://doi.org/10.1177/0963693519875974
Gómez-Carracedo, A., Alvarez-Lorenzo, C., Coca, R., Martínez-Pacheco, R., Concheiro, A., & Gómez-Amoza, J. L. (2009). Fractal analysis of SEM images and mercury intrusion porosimetry data for the microstructural characterization of microcrystalline cellulose-based pellets. Acta Materialia, 57(1), 295–303. https://doi.org/10.1016/j.actamat.2008.09.009
Gupta, M. C., & Iqbal, M. (2005). Ontogenetic histological changes in the wood of mango (Mangifera indica L. cv Deshi) exposed to coal-smoke pollution. Environmental and Experimental Botany, 54(3), 248–255. https://doi.org/10.1016/j.envexpbot.2004.09.003
Gurgel, L. V. A., Júnior, O. K., Gil, R. P. de F., & Gil, L. F. (2008). Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by cellulose and mercerized cellulose chemically modified with succinic anhydride. Bioresource Technology, 99(8), 3077–3083. https://doi.org/10.1016/j.biortech.2007.05.072
Halasz, I., Agarwal, M., & Miller, N. (2010). What can vibrational spectroscopy tell about the structure of dissolved sodium silicates? Microporus and Mesoporous Materials, 135, 74–81.
Han, S., Lyu, S., Chen, Z., Wang, S., & Fu, F. (2019). Fabrication of melamine–urea–formaldehyde/paraffin microcapsules modified with cellulose nanocrystals via in situ polymerization. Journal of Materials Science, 54(9), 7383–7396. https://doi.org/10.1007/s10853-019-03352-8
Haque, A. N. M. A., Remadevi, R., Rojas, O. J., Wang, X., & Naebe, M. (2020). Kinetics and equilibrium adsorption of methylene blue onto cotton gin trash bioadsorbents. Cellulose, 27(11), 6485–6504. https://doi.org/10.1007/s10570-020-03238-y
Hazarika, A., Deka, B. K., & Maji, T. K. (2015). Melamine-formaldehyde acrylamide and gum polymer impregnated wood polymer nanocomposite. Journal of Bionic Engineering, 12(2), 304–315. https://doi.org/10.1016/S1672-6529(14)60123-2
Henriksson, M., & Berglund, L. A. (2007). Structure and Properties of Cellulose Nanocomposite Films Containing Melamine Formaldehyde. Journal of Applied Polymer Science, 106, 2817–2824. https://doi.org/10.1002/app.26946
Ho, Y. S., Porter, J. F., & Mckay, G. (2002). Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component systems. Water, Air, & Soil Pollution, 141(1–4), 1–33.
Husson, E., Buchoux, S., Avondo, C., Cailleu, D., Djellab, K., Gosselin, I., Wattraint, O., & Sarazin, C. (2011). Enzymatic hydrolysis of ionic liquid-pretreated celluloses: Contribution of CP-MAS 13C NMR and SEM. Bioresource Technology, 102(15), 7335–7342. https://doi.org/10.1016/j.biortech.2011.04.097
Jawaid, S., Talpur, F. N., Afridi, H. I., Nizamani, S. M., Khaskheli, A. A., & Naz, S. (2014). Quick determination of melamine in infant powder and liquid milk by Fourier transform infrared spectroscopy. Analytical Methods, 6(14), 5269–5273. https://doi.org/10.1039/c4ay00558a
Júnior, O. K., Gurgel, L. V. A., de Freitas, R. P., & Gil, L. F. (2009). Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse chemically modified with EDTA dianhydride (EDTAD). Carbohydrate Polymers, 77(3), 643–650. https://doi.org/10.1016/j.carbpol.2009.02.016
Kabir, M. M., Wang, H., Lau, K. T., & Cardona, F. (2012). Chemical treatments on plant-based natural fibre reinforced polymer composites: An overview. Composites Part B: Engineering, 43(7), 2883–2892. https://doi.org/10.1016/j.compositesb.2012.04.053
Kamble, Z., Behera, B. K., Mishra, R., & Behera, P. K. (2021). Influence of cellulosic and non-cellulosic particle fillers on mechanical, dynamic mechanical, and thermogravimetric properties of waste cotton fibre reinforced green composites. Composites Part B: Engineering, 207(September 2020), 108595. https://doi.org/10.1016/j.compositesb.2020.108595
Kanemaru, T., Hirata, K., Takasu, S. I., Isobe, S. I., Mizuki, K., Mataka, S., & Nakamura, K. I. (2010). A fluorescence scanning electron microscope. Materials Today, 12(SUPPL.), 18–23. https://doi.org/10.1016/S1369-7021(10)70141-3
Kapur, M., & Mondal, M. K. (2013). Mass transfer and related phenomena for Cr(VI) adsorption from aqueous solutions onto Mangifera indica sawdust. Chemical Engineering Journal, 218, 138–146. https://doi.org/10.1016/j.cej.2012.12.054
Keshk, S. M. A. S., & Hamdy, M. S. (2019). Preparation and physicochemical characterization of zinc oxide/sodium cellulose composite for food packaging. Turkish Journal of Chemistry, 43(1), 94–105. https://doi.org/10.3906/kim-1803-83
Krishnamachari, P., Hashaikeh, R., & Tiner, M. (2011). Modified cellulose morphologies and its composites; SEM and TEM analysis. Micron, 42(8), 751–761. https://doi.org/10.1016/j.micron.2011.05.001
Kwiecińska, B., Pusz, S., & Valentine, B. J. (2019). Application of electron microscopy TEM and SEM for analysis of coals, organic-rich shales and carbonaceous matter. International Journal of Coal Geology, 211(May), 103203. https://doi.org/10.1016/j.coal.2019.05.010
Laskar, I. B., Gupta, R., Chatterjee, S., Vanlalveni, C., & Rokhum, L. (2020). Taming waste: Waste Mangifera indica peel as a sustainable catalyst for biodiesel production at room temperature. Renewable Energy, 161, 207–220. https://doi.org/10.1016/j.renene.2020.07.061
Li, Y., Cui, W., Liu, L., Zong, R., Yao, W., Liang, Y., & Zhu, Y. (2016). Removal of Cr(VI) by 3D TiO2-graphene hydrogel via adsorption enriched with photocatalytic reduction. Applied Catalysis B: Environmental, 199, 412–423. https://doi.org/10.1016/j.apcatb.2016.06.053
Lutzke, A., Morey, K. J., Medford, J. I., & Kipper, M. J. (2020). An FT-IR and XPS spectroscopy dataset of Pinus ponderosa sporopollenin and related samples to elucidate sporopollenin structural features. Data in Brief, 29(January), 105129. https://doi.org/10.1016/j.dib.2020.105129
Lyu, R., Zhang, C., Xia, T., Chen, S., Wang, Z., Luo, X., Wang, L., Wang, Y., Yu, J., & Wang, C. W. (2020). Efficient adsorption of methylene blue by mesoporous silica prepared using sol-gel method employing hydroxyethyl cellulose as a template. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 606(May), 125425. https://doi.org/10.1016/j.colsurfa.2020.125425
Marzouki, R., Brahmia, A., Bondock, S., Keshk, S. M. A. S., Zid, M. F., Al-Sehemi, A. G., Koschella, A., & Heinze, T. (2019). Mercerization effect on structure and electrical properties of cellulose: Development of a novel fast Na-ionic conductor. Carbohydrate Polymers, 221(March), 29–36. https://doi.org/10.1016/j.carbpol.2019.05.083
Meira, A. M. (2010). Gestão de resíduos de arborização urbana. Escola Superior de Agricultura “Luiz de Queiroz.”
Merline, D. J., Vukusic, S., & Abdala, A. A. (2013). Melamine formaldehyde: Curing studies and reaction mechanism. Polymer Journal, 45(4), 413–419. https://doi.org/10.1038/pj.2012.162
Moghazy, R. M., Labena, A., & Husien, S. (2019). Eco-friendly complementary biosorption process of methylene blue using micro-sized dried biosorbents of two macro-algal species (Ulva fasciata and Sargassum dentifolium): Full factorial design, equilibrium, and kinetic studies. International Journal of Biological Macromolecules, 134, 330–343. https://doi.org/10.1016/j.ijbiomac.2019.04.207
Nagarajan, D., Varada, O. M., & Venkatanarasimhan, S. (2020). Carbon dots coated on amine functionalized cellulose sponge for the adsorption of the toxic herbicide atrazine. Materials Today: Proceedings, xxxx. https://doi.org/10.1016/j.matpr.2020.08.071
Pathania, D., Sharma, A., & Srivastava, A. K. (2020). Modelling studies for remediation of Cr (VI) from wastewater by activated Mangifera indica bark. In Current Research in Green and Sustainable Chemistry (Vol. 3, Issue Vi). Elsevier B.V. https://doi.org/10.1016/j.crgsc.2020.100034
Pavan, F. A., Lima, E. C., Dias, S. L. P., & Mazzocato, A. C. (2008). Methylene blue biosorption from aqueous solutions by yellow passion fruit waste. Journal of Hazardous Materials, 150(3), 703–712. https://doi.org/10.1016/j.jhazmat.2007.05.023
Poletto, M., Zattera, A. J., & Santana, R. M. C. (2012). Thermal decomposition of wood: Kinetics and degradation mechanisms. Bioresource Technology, 126, 7–12. https://doi.org/10.1016/j.biortech.2012.08.133
Rehman, A., & Park, S. J. (2018). Highlighting the relative effects of surface characteristics and porosity on CO2 capture by adsorbents templated from melamine-based polyaminals. Journal of Solid State Chemistry, 258(November 2017), 573–581. https://doi.org/10.1016/j.jssc.2017.11.019
Rizvi, S., Goswami, L., & Gupta, S. K. (2020). A holistic approach for melanoidin removal via Fe-impregnated activated carbon prepared from Mangifera indica leaves biomass. Bioresource Technology Reports, 12(August), 100591. https://doi.org/10.1016/j.biteb.2020.100591
Sahiner, N., Demirci, S., & Sel, K. (2016). Covalent organic framework based on melamine and dibromoalkanes for versatile use. Journal of Porous Materials, 23(4), 1025–1035. https://doi.org/10.1007/s10934-016-0160-9
Saleh, T. A., Sarı, A., & Tuzen, M. (2017). Effective adsorption of antimony(III) from aqueous solutions by polyamide-graphene composite as a novel adsorbent. Chemical Engineering Journal, 307, 230–238. https://doi.org/10.1016/j.cej.2016.08.070
Seo, P. W., Khan, N. A., Hasan, Z., & Jhung, S. H. (2016). Adsorptive Removal of Artificial Sweeteners from Water Using Metal-Organic Frameworks Functionalized with Urea or Melamine. ACS Applied Materials and Interfaces, 8(43), 29799–29807. https://doi.org/10.1021/acsami.6b11115
Sharifi, F., Jahangiri, M., Nazir, I., Asim, M. H., Ebrahimnejad, P., Hupfauf, A., Gust, R., & Bernkop-Schnürch, A. (2021). Zeta potential changing nanoemulsions based on a simple zwitterion. Journal of Colloid and Interface Science, 585, 126–137. https://doi.org/10.1016/j.jcis.2020.11.054
Shen, L., Zhang, H., Lei, Y., Chen, Y., Liang, M., & Zou, H. (2021). Hierarchical pore structure based on cellulose nanofiber/melamine composite foam with enhanced sound absorption performance. Carbohydrate Polymers, 255(October 2020), 117405. https://doi.org/10.1016/j.carbpol.2020.117405
Singh, B., Gupta, M., Verma, A., & Tyagi, O. S. (2000). FT-IR microscopic studies on coupling agents: Treated natural fibres. Polymer International, 49(11), 1444–1451. https://doi.org/10.1002/1097-0126(200011)49:11<1444::AID-PI526>3.0.CO;2-9
Sreekala, M. S., & Thomas, S. (2003). Effect of fibre surface modification on water-sorption characteristics of oil palm fibres. Composites Science and Technology, 63(6), 861–869. https://doi.org/10.1016/S0266-3538(02)00270-1
Tang, R., Dai, C., Li, C., Liu, W., Gao, S., & Wang, C. (2017). Removal of Methylene Blue from Aqueous Solution Using Agricultural Residue Walnut Shell: Equilibrium, Kinetic, and Thermodynamic Studies. Journal of Chemistry, 2017. https://doi.org/10.1155/2017/8404965
Tsai, W. T., Yang, J. M., Lai, C. W., Cheng, Y. H., Lin, C. C., & Yeh, C. W. (2006). Characterization and adsorption properties of eggshells and eggshell membrane. Bioresource Technology, 97(3), 488–493. https://doi.org/10.1016/j.biortech.2005.02.050
Ullah, S., Bustam, M. A., Ahmad, F., Nadeem, M., Naz, M. Y., Sagir, M., & Shariff, A. M. (2015). Synthesis and characterization of melamine formaldehyde resins for decorative paper applications. Journal of the Chinese Chemical Society, 62(2), 182–190. https://doi.org/10.1002/jccs.201400226
Vieira, J. G., Filho, G. R., Meireles, C. D. S., Faria, F. A. C., Gomide, D. D., Pasquini, D., Cruz, S. F. D., De Assunção, R. M. N., & Motta, L. A. D. C. (2012). Synthesis and characterization of methylcellulose from cellulose extracted from mango seeds for use as a mortar additive. Polimeros, 22(1), 80–87. https://doi.org/10.1590/S0104-14282012005000011
Wang, N., Chen, J., Wang, J., Feng, J., & Yan, W. (2019). Removal of methylene blue by Polyaniline/TiO 2 hydrate: Adsorption kinetic, isotherm and mechanism studies. Powder Technology, 347, 93–102. https://doi.org/10.1016/j.powtec.2019.02.049
Xiong, Y., Tong, Q., Shan, W., Xing, Z., Wang, Y., Wen, S., & Lou, Z. (2017). Arsenic transformation and adsorption by iron hydroxide/manganese dioxide doped straw activated carbon. Applied Surface Science, 416, 618–627. https://doi.org/10.1016/j.apsusc.2017.04.145
Yu, Y., Liu, S., Pei, Y., & Luo, X. (2021). Growing Pd NPs on cellulose microspheres via in-situ reduction for catalytic decolorization of methylene blue. International Journal of Biological Macromolecules, 166, 1419–1428. https://doi.org/10.1016/j.ijbiomac.2020.11.021
Zeng, Q., Hao, T., Yuan, Z., & Chen, G. (2020). Dewaterability enhancement and sul fi de mitigation of CEPT sludge by electrochemical pretreatment. Water Research, 176, 115727. https://doi.org/10.1016/j.watres.2020.115727
Zhang, H., & Wang, X. (2009). Fabrication and performances of microencapsulated phase change materials based on n-octadecane core and resorcinol-modified melamine-formaldehyde shell. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 332(2–3), 129–138. https://doi.org/10.1016/j.colsurfa.2008.09.013
Zhang, Q., Zhang, Z., Teng, J., Huang, H., Peng, Q., Jiao, T., Hou, L., & Li, B. (2015). Highly efficient phosphate sequestration in aqueous solutions using nanomagnesium hydroxide modified polystyrene materials. Industrial and Engineering Chemistry Research, 54(11), 2940–2949. https://doi.org/10.1021/ie503943z
Zhang, Z., Zhu, M., & Zhang, D. (2018). A Thermogravimetric study of the characteristics of pyrolysis of cellulose isolated from selected biomass. Applied Energy, 220(March), 87–93. https://doi.org/10.1016/j.apenergy.2018.03.057
Zhao, H., Kwak, J. H., Conrad Zhang, Z., Brown, H. M., Arey, B. W., & Holladay, J. E. (2007). Studying cellulose fiber structure by SEM, XRD, NMR and acid hydrolysis. Carbohydrate Polymers, 68(2), 235–241. https://doi.org/10.1016/j.carbpol.2006.12.013
Zimmermann, T., Bordeanu, N., & Strub, E. (2010). Properties of nanofibrillated cellulose from different raw materials and its reinforcement potential. Carbohydrate Polymers, 79(4), 1086–1093. https://doi.org/10.1016/j.carbpol.2009.10.045
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Derechos de autor 2021 Jarbas Soares de Mesquita Júnior; Francisco Cardoso Figueiredo; Evânia Carvalho dos Santos; Darlisson Slag Neri Silva; José Ribeiro dos Santos Júnior
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